Figures and Tables

From the following article:

Biologically inspired oxidation catalysis

Lawrence Que, Jr & William B. Tolman

Nature 455, 333-340(18 September 2008)

doi:10.1038/nature07371

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Figure 1

Metallo-oxygenase mechanisms.

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Figure 2

Metalloenzyme intermediates.

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Figure 3

Galactose oxidase mechanism.

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Figure 4

Ligands for modelling GAO.

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Figure 5

Copper–TEMPO radical oxidation.

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Figure 6

Proposed mechanism for alcohol oxidation.

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Figure 7

Oxidations by dicopper complexes.

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Figure 8

Ligands used for iron- and manganese-catalysed oxidations.

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Figure 9

Mechanisms of oxidations by iron catalysts.

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Figure 10

Illustrative selective oxidations by iron.

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Table 1

Iron and manganese oxidation catalysts that use H2O2 as the oxidant to give high conversion of alkenes into epoxide or cis-diol products

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