Figures and Tables

From the following article:

Carbon–heteroatom bond formation catalysed by organometallic complexes

John F. Hartwig

Nature 455, 314-322(18 September 2008)

doi:10.1038/nature07369

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Figure 1

Catalytic C–C and C–H bond-forming processes.

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Figure 2

Mechanisms of three common catalytic organometallic processes.

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Figure 3

Recently discovered organometallic reactions of transition-M–heteroatom bonds.

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Figure 4

Aspects of palladium-catalysed amination of aryl halides and related reactions.

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Figure 5

Organometallic oxidative C–O and C–halogen bond-forming functionalization of C–H bonds.

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Figure 6

Summary of the functionalization of alkanes with M–B intermediates.

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Figure 7

Organometallic oxidation and oxidative amination of olefins.

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Figure 8

Two mechanisms for catalytic hydroaminations of C–C multiple bonds through M–amido intermediates.

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Figure 9

Data and basis for relative rates of olefin insertion into alkyl, amide and alkoxo complexes.

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