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Nature 450, 1206-1209 (20 December 2007) | doi:10.1038/nature06428; Received 12 July 2007; Accepted 24 October 2007

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Late formation and prolonged differentiation of the Moon inferred from W isotopes in lunar metals

M. Touboul1, T. Kleine1, B. Bourdon1, H. Palme2 & R. Wieler1

  1. Institute for Isotope Geochemistry and Mineral Resources, Department of Earth Sciences, Eidgenössische Technische Hochschule Zurich, Clausiusstrasse 25, 8092 Zurich, Switzerland
  2. Institut für Mineralogie und Geochemie, Universität zu Köln, Zülpicherstrasse 49b, 50674 Köln, Germany

Correspondence to: M. Touboul1 Correspondence and requests for materials should be addressed to M.T. (Email: touboul@erdw.ethz.ch).

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The Moon is thought to have formed from debris ejected by a giant impact with the early 'proto'-Earth1 and, as a result of the high energies involved, the Moon would have melted to form a magma ocean. The timescales for formation and solidification of the Moon can be quantified by using 182Hf–182W and 146Sm–142Nd chronometry2, 3, 4, but these methods have yielded contradicting results. In earlier studies3, 5, 6, 7, 182W anomalies in lunar rocks were attributed to decay of 182Hf within the lunar mantle and were used to infer that the Moon solidified within the first approx60 million years of the Solar System. However, the dominant 182W component in most lunar rocks reflects cosmogenic production mainly by neutron capture of 181Ta during cosmic-ray exposure of the lunar surface3, 7, compromising a reliable interpretation in terms of 182Hf–182W chronometry. Here we present tungsten isotope data for lunar metals that do not contain any measurable Ta-derived 182W. All metals have identical 182W/184W ratios, indicating that the lunar magma ocean did not crystallize within the first approx60 Myr of the Solar System, which is no longer inconsistent with Sm–Nd chronometry8, 9, 10, 11. Our new data reveal that the lunar and terrestrial mantles have identical 182W/184W. This, in conjunction with 147Sm–143Nd ages for the oldest lunar rocks8, 9, 10, 11, constrains the age of the Moon and Earth to Unfortunately we are unable to provide accessible alternative text for this. If you require assistance to access this image, or to obtain a text description, please contact npg@nature.com Myr after formation of the Solar System. The identical 182W/184W ratios of the lunar and terrestrial mantles require either that the Moon is derived mainly from terrestrial material or that tungsten isotopes in the Moon and Earth's mantle equilibrated in the aftermath of the giant impact, as has been proposed to account for identical oxygen isotope compositions of the Earth and Moon12.

  1. Institute for Isotope Geochemistry and Mineral Resources, Department of Earth Sciences, Eidgenössische Technische Hochschule Zurich, Clausiusstrasse 25, 8092 Zurich, Switzerland
  2. Institut für Mineralogie und Geochemie, Universität zu Köln, Zülpicherstrasse 49b, 50674 Köln, Germany

Correspondence to: M. Touboul1 Correspondence and requests for materials should be addressed to M.T. (Email: touboul@erdw.ethz.ch).

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