Nature 449, 702-705 (11 October 2007) | doi:10.1038/nature06139; Received 5 June 2007; Accepted 27 July 2007

Observation of ferrotoroidic domains

Bas B. Van Aken1,2, Jean-Pierre Rivera3, Hans Schmid3 & Manfred Fiebig1,2

  1. Max-Born-Institut, Max-Born-Stras zlige 2A, 12489 Berlin, Germany
  2. HISKP, Universität Bonn, Nussallee 14-16, 53115 Bonn, Germany
  3. Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, 30 quai Ernest-Ansermet, 1211 Geneva 4, Switzerland

Correspondence to: Manfred Fiebig1,2 Correspondence and requests for materials should be addressed to M.F. (Email: fiebig@hiskp.uni-bonn.de).

Domains are of unparalleled technological importance as they are used for information storage and for electronic, magnetic and optical switches. They are an essential property of any ferroic material. Three forms of ferroic order are widely known: ferromagnetism, a spontaneous magnetization; ferroelectricity, a spontaneous polarization; and ferroelasticity, a spontaneous strain. It is currently debated whether to include an ordered arrangement of magnetic vortices as a fourth form of ferroic order, termed ferrotoroidicity. Although there are reasons to expect this form of order from the point of view of thermodynamics1, a crucial hallmark of the ferroic state—that is, ferrotoroidic domains—has not hitherto been observed. Here ferrotoroidic domains are spatially resolved by optical second harmonic generation in LiCoPO4, where they coexist with independent antiferromagnetic domains. Their space- and time-asymmetric nature relates ferrotoroidics to multiferroics with magnetoelectric phase control2, 3, 4, 5 and to other systems in which space and time asymmetry leads to possibilities for future applications.


These links to content published by NPG are automatically generated.


Supplementary Information

Nature Materials Letter (01 Apr 2010)

Magnetic phase control by an electric field

Nature Letters to Editor (29 Jul 2004)

See all 25 matches for Research