Abstract
The magnetoelectric effect—the induction of magnetization by means of an electric field and induction of polarization by means of a magnetic field—was first presumed to exist by Pierre Curie1, and subsequently attracted a great deal of interest in the 1960s and 1970s (refs 2–4). More recently, related studies on magnetic ferroelectrics5,6,7,8,9,10,11,12,13,14 have signalled a revival of interest in this phenomenon. From a technological point of view, the mutual control of electric and magnetic properties is an attractive possibility15, but the number of candidate materials is limited and the effects are typically too small to be useful in applications. Here we report the discovery of ferroelectricity in a perovskite manganite, TbMnO3, where the effect of spin frustration causes sinusoidal antiferromagnetic ordering. The modulated magnetic structure is accompanied by a magnetoelastically induced lattice modulation, and with the emergence of a spontaneous polarization. In the magnetic ferroelectric TbMnO3, we found gigantic magnetoelectric and magnetocapacitance effects, which can be attributed to switching of the electric polarization induced by magnetic fields. Frustrated spin systems therefore provide a new area to search for magnetoelectric media.
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References
Curie, P. Sur la symétrie dans les phénomenes physiques, symétrie d'un champ électrique et d'un champ magnétique. J. Phys. 3(Ser. III), 393–415 (1894)
O'Dell,, T. H. The Electrodynamics of Magneto-Electric Media (North-Holland, Amsterdam, 1970)
Freeman, A. J. & Schmid, H. (eds) Magnetoelectric Interaction Phenomena in Crystals (Gordon and Breach, London, 1975)
Smolenskii, G. A. & Chupis, I. E. Ferroelectromagnets. Usp. Fiz. Nauk. 137, 415–448 (1982); also Sov. Phys. Usp. 25, 475–493 (1982)
Huang, Z. J., Cao, Y., Sun, Y., Xue, Y. Y. & Chu, C. W. Coupling between the ferroelectric and antiferromagnetic orders in YMnO3 . Phys. Rev. B 56, 2623–2626 (1997)
Iwata, N. & Kohn, K. Dielectric anomalies at magnetic transitions of hexagonal rare earth manganese oxides RMnO3 . J. Phys. Soc. Jpn 67, 3318–3319 (1998)
Katsufuji, T. et al. Dielectric and magnetic anomalies and spin frustration in hexagonal RMnO3 (R = Y, Yb, and Lu). Phys. Rev. B 64, 104419 (2001)
Fiebig, M., Lottermoser, Th., Fröhlich, D., Goltsev, A. V. & Pisarev, R. V. Observation of coupled magnetic and electric domains. Nature 419, 818–820 (2002)
Hanamura, E., Hagita, K. & Tanabe, Y. Clamping of ferroelectric and antiferromagnetic order parameters of YMnO3 . J. Phys. Condens. Matter 14, L103–L109 (2003)
Zhong, C. G. & Jiang, Q. The study of the coupling mechanism between antiferromagnetic and ferroelectric ordering and thermodynamic properties in ferroelectromagnets. J. Phys. Condens. Matter 14, 8605–8612 (2002)
Seshadri, R. & Hill, N. A. Visualizing the role of Bi 6s “lone pairs” in the off-center distortion in ferromagnetic BiMnO3 . Chem. Mater. 13, 2892–2899 (2001)
Moreira dos Santos, A. et al. Evidence for the likely occurrence of magnetoferroelectricity in the simple perovskite, BiMnO3 . Solid State Commun. 122, 49–52 (2002)
Kimura, T. et al. Magnetocapacitance effect in multiferroic BiMnO3 . Phys. Rev. B 67, 180401(R) (2003)
Wang, J. et al. Epitaxial BiFeO3 multiferroic thin film heterostructures. Science 299, 1719–1722 (2003)
Wood, V. E. & Austin, A. E. Possible applications for magnetoelectric materials. Int. J. Magn. 5, 303–315 (1974)
Quezel, S., Tcheou, F., Rossat-Mignod, J., Quezel, G. & Roudaut, E. Magnetic structure of the perovskite-like compound TbMnO3 . Physica B 86–88, 916–918 (1977)
Kimura, T. et al. Distorted perovskite with e g1 configuration as a frustrated spin system. Phys. Rev. B 68, 060403(R) (2003)
Greenwald, S. & Smart, J. S. Deformations in the crystal structures of anti-ferromagnetic compounds. Nature 166, 523–524 (1950)
Smart, J. S. & Greenwald, S. Crystal structure transitions in antiferromagnetic compounds at the Curie temperature. Phys. Rev. 82, 113–114 (1951)
Bohr, J. et al. Diffraction studies of rare earth metals and superlattices. Physica B 159, 93–105 (1989)
Bohr, J., Gibbs, D. & Huang, K. X-ray-diffraction studies of the magnetic state of thulium. Phys. Rev. B 42, 4322–4328 (1990)
Blinc, R. & Levanyuk, A. P. Incommensurate Phases in Dielectrics 1. Fundamentals (North-Holland, Amsterdam, 1986)
Levanyuk, A. P. & Sannikov, D. G. Improper ferroelectrics. Usp. Fiz. Nauk. 112, 561–589 (1974); also Sov. Phys. Usp. 17, 199–214 (1974)
Sawada, S., Shiroishi, Y., Yamamoto, A., Takashige, M. & Matsuo, M. Ferroelectricity in Rb2ZnCl4 . J. Phys. Soc. Jpn 43, 2099–2100 (1977)
Aiki, K., Hukuda, K. & Matumura, O. Ferroelectricity in K2SeO4 . J. Phys. Soc. Jpn 26, 1064 (1969)
Goldsmith, G. J. & White, J. G. Ferroelectric behavior in thiourea. J. Chem. Phys. 31, 1175–1187 (1959)
Bouree, J. E. & Hammann, J. Mise en évidence expérimentale des effets de forme dans l'orthoferrite de terbium. J. Phys. 36, 391–397 (1975)
Bidaux, R., Bouree, J. E. & Hammann, J. Diagramme de phase de l'orthoferrite de terbium en présence d'un champ magnétique. J. Phys. 36, 803–809 (1975)
Acknowledgements
We thank K. Kohn, K. Ohgushi, S. Ishihara and A. P. Ramirez for discussions, and Y. Wakabayashi for help with X-ray diffraction measurements. This work was partly supported by KAKENHI from the MEXT of Japan.
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Kimura, T., Goto, T., Shintani, H. et al. Magnetic control of ferroelectric polarization. Nature 426, 55–58 (2003). https://doi.org/10.1038/nature02018
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DOI: https://doi.org/10.1038/nature02018
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