1. Department of Materials Science and Metallurgy, University of Cambridge , Pembroke Street, Cambridge CB2 3QZ , UK

Correspondence to: G. T. Burstein Correspondence and requests for materials should be addressed to G.T.B. (e-mail: Email: gtb1000@cus.cam.ac.uk).

Abstract

Modification of the surface properties of metals without affecting their bulk properties is of technological interest in demanding applications where surface stability and hardness are important. When austenitic stainless steel is heavily plastically deformed by grinding or rolling, a martensitic phase transformation occurs that causes significant changes in the bulk and surface mechanical properties^{1, 2, 3, 4, 5, 6, 7, 8, 9} of the alloy. This martensitic phase can also be generated in stainless-steel surfaces by cathodic charging, as a consequence of lattice strain generated by absorbed hydrogen^{10, 11, 12, 13, 14, 15, 16}. Heat treatment of the steel to temperatures of several hundred degrees can result in loss of the martensitic structure¹, but this alters the bulk properties of the alloy. Here we show that martensitic structures in stainless steel can be removed by appropriate electrochemical treatment in aqueous solutions at much lower temperature than conventional annealing treatments. This electrochemically induced annealing process allows the hardness of cold-worked stainless steels to be maintained, while eliminating the brittle martensitic phase from the surface. Using this approach, we are able to anneal the surface and near-surface regions of specimens that contain rolling-induced martensite throughout their bulk, as well as those containing surface martensite induced by grinding. Although the origin of the electrochemical annealing process still needs further clarification, we expect that this treatment will lead to further development in enhancing the surface properties of metals.