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Molecular fractal surfaces

Abstract

In this letter we report that, at the molecular-size range, the surfaces of most materials are fractals, that is, at this range, surface geometric irregularities and defects are characteristically self-similar upon variations of resolution. The whole range of fractal dimension1, 2D<3, is found in the many examples presented. Two representative examples, namely adsorption of polystyrene on alumina and adsorption of krypton on dolomite are discussed in some detail. Our findings suggest a simple solution to the problem of quantifying the degree of surface irregularity2,3 at a resolution which is of relevance to many aspects of surface science. The results provide a general explanation for phenomenological links between various surface parameters, and we derive a set of equations of use in predicting surface variables.

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Avnir, D., Farin, D. & Pfeifer, P. Molecular fractal surfaces. Nature 308, 261–263 (1984). https://doi.org/10.1038/308261a0

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