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Formation of Beryllium Carbide during the Corrosion of Beryllium in Carbon Monoxide and in Carbon Dioxide Gas

Abstract

PREVIOUS workers1 have concluded from a comparison of the reaction between beryllium in dry carbon dioxide at 650° C. and in dry oxygen at 650° C. under kinetic conditions that the higher gain in weight of the specimen in carbon dioxide was due to the formation of beryllium carbide, which rendered the beryllium oxide non-protective. However, no metallographic evidence for the deposition on to the specimen of carbon, either as elementary carbon or as carbide, was given to support their hypothesis.

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References

  1. Munro, W., and Williams, J., A.E.R.E. Report M/M108 (1956).

  2. Swanson, H. E., and Tatge, E., Nat. Bur. Stand. (U.S.A.), Circ. 539, 1, 36.

  3. von Stackelberg, M., and Quatram, F., Z. phys. Chem., B, 27, 51 (1934).

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  4. Kubaschewski, O., and Evans, E. Ll., “Metallurgical Thermochemistry” (Pergamon Press, London, 1956).

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SCOTT, V. Formation of Beryllium Carbide during the Corrosion of Beryllium in Carbon Monoxide and in Carbon Dioxide Gas. Nature 186, 466–467 (1960). https://doi.org/10.1038/186466a0

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  • DOI: https://doi.org/10.1038/186466a0

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