Abstract
THE accelerated oxidation of cellulose in the presence of ferrous hydroxide by dilute solutions of sodium hypochlorite, buffered to different hydrogen ion concentrations, has been studied by Nabar and Turner1. It was shown that the maximum absorption of oxygen and the maximum attack on cellulose occurred at about pH. 6.4. From similar earlier investigations, with leuco vat dyes as accelerators, Nabar, Scholefield and Turner2,3 had shown that the maximum oxygen uptake and the maximum oxidation of cellulose occurred at about pH. 7.4. The obvious dependence of the oxidizing intensity of sodium hypochlorite solutions on the specific substance present on cellulose may be attributed to the differences in their physico-chemical properties, such as reduction potentials, ease of oxidation, etc. The present work was undertaken to study the reduction potential of ferrous hydroxide and examine its influence on the oxidation mechanism.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Nabar and Turner, J. Soc. Dyers and Colour., 61, 258 (1945).
Turner, Nabar and Scholefield, J. Soc. Dyers and Colour., 51, 5 (1935).
Nabar, Scholefield and Turner, J. Soc. Dyers and Colour., 53, 5 (1937).
Foust, O., Z. Electrochem., 13, 160 (1907).
Forster and Herold, Z. Electrochem., 11, 949 (1905).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
MHATRE, S., NABAR, G. Reduction Potentials of Ferrous Hydroxide. Nature 159, 372–373 (1947). https://doi.org/10.1038/159372b0
Issue Date:
DOI: https://doi.org/10.1038/159372b0
This article is cited by
-
Accelerated oxidation of cotton cellulose in presence of reducing substances—Part III
Proceedings of the Indian Academy of Sciences - Section A (1951)
-
Studies in oxycellulose
Proceedings of the Indian Academy of Sciences - Section A (1950)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.