nature 156, 53-53 (14 July 1945) | doi:10.1038/156053a0

Halogenation in the Allyl Position

WILLIAM E. VAUGHAN ,  FREDERICK F. RUST &  GEORGE W. HEARNE

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WE should like to make a few comments on the recent communication by W. A. Waters1 in criticism of F. S. Spring2 for stating that substitution in the allyl position of olefines is a new reaction attributable to Ziegler and his collaborators3.

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References

  1. Nature, 154, 772 (1944).
  2. Annual Reports of the Chemical Society, 40, 101 (1943).
  3. Annalen der Chemie, 551, 80 (1942).
  4. Groll and Hearne, Ind. Eng. Chem., 31, 1530 (1939). Engs and Redmond, U.S. Patent 2,077,382, April 20, 1937. Groll, Hearne, Burgin and LaFrance, U.S. Patent 2,130,084, September 13, 1938.
  5. Trans. Faraday Soc., 38, 340 (1942).
  6. J. Org. Chem., 5, 472 (1940).
  7. Trans. Faraday Soc., 37, 791 (1941).
  8. Trans. Faraday Soc., 37, 792 (1941).
  9. See Mayo and Walling, Chem. Rev., 87, 351 (1940).
  10. Vaughan and Rust, J. Org. Chem., 7, 472, 477 (1942).
  11. See, for example, ref. (9), (p. 358); also, Weiss, Trans. Faraday Soc., 37, 793 (1941).
  12. For example, see references (5) and (8).

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