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Evaluation of ambient air concentrations of polycyclic aromatic hydrocarbons in Germany from 1990 to 1998

Journal of Exposure Science & Environmental Epidemiology volume 12, pages 115–123 (2002)Cite this article

Abstract

All available polycyclic aromatic hydrocarbon (PAH) concentration data in ambient air obtained over the past 10 years in Germany were evaluated to clarify whether it is justified to use benzo(a)pyrene (BaP) as a marker compound for the total PAH exposure. The data basis comprises annual mean concentrations from 1990 to 1998 supplied by the emission protection authorities of the federal states with additional information on the region, year and site of measurement. The data are very heterogeneous with respect to sample size, the number of individual PAHs analyzed, place of origin and year. Nine of 25 individual compounds with sufficient sample size (74<N<518) were submitted to an explorative descriptive analysis and multiple regression analysis. Six compounds were selected for factor analysis to evaluate whether associations can be related to one or several background determinants. The concentration data of BaA, BeP, BaP, DBA, BghiP, COR, BbF, BkF and INP are not normally distributed and demonstrate great variability. Location, East–West differences persisting after the German reunion and time characterize the distributive patterns, e.g., from 1991 to 1997, a significant decrease in BaP could be determined based on the data from North Rhine-Westphalia (1991, N=51, median 1.6 ng/m3; 1997, N=45, median 0.7 ng/m3; P≤0.0001). The BaP concentrations in the new federal states in the East (N=80, median 2.2 ng/m3) are about twice as high compared to the ones in the old federal states in the West (N=438, median 1.1 ng/m3; P≤0.0001). BaP measurements taken at sites characterized by traffic (1.8 ng/m3), industrial (1.3 ng/m3) or urban environment (1.3 ng/m3) rank significantly higher compared to measurements taken at rural sites (0.92 ng/m3; P≤0.0001). Factor analysis of the intercorrelation matrix of BaA, BeP, BaP, DBA, BghiP and COR yields one factor to explain 92% of the variability of the six individual PAHs. BaP shows the highest factor loading. These results confirm the common practice to use BaP as marker compound for the PAH exposure in ambient air.

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References

  • Brosius G Brosius F, 1995 SPSS Base System and Professional Statistics. International Thomson Publishing, Bonn 1995

    Google Scholar 

  • deRaat WK de Meijere FA Polycyclic aromatic hydrocarbon (PAH) concentrations in ambient airborne particles from local traffic and distant sources; variation of the PAH profile, Sci Total Environ (1995) 103(1): 1–17

    Article  Google Scholar 

  • Fertmann R Tesseraux I Schümann M Neus H Prinz B, 1999. Auswertung der in der BRD vorliegenden Immissionsmessdaten von polyzyklischen aromatischen Kohlenwasserstoffen (1990–1998), Bericht im Auftrag des Unterausschusses Wirkungsfragen des Länderausschusses für Immissionsschutz (LAI), Hamburg (1999)

  • Gladtke D Air pollution in the Rhine-Ruhr area, Toxicol Lett (1998) 96: 277–283

    Article  Google Scholar 

  • Grimmer G Vergleich der PAH-Profile aus Umweltproben, VDI Report 358. VDI-Verlag, Düsseldorf 1980 39–50

    Google Scholar 

  • Heudorf U Schubert W Innenraumbelastung mit polycyclischen aromatischen Kohlenwasserstoffen (PAK) durch PAK-haltige Parkettklebstoffe-Hinweise der Projektgruppe Schadstoffe der Bauministerkonferenz, Umweltmed Forsch Prax (2000) 5: 341–344

    CAS  Google Scholar 

  • International Agency for Research on Cancer (IARC) 1987. Overall evaluation of carcinogenicity. An updating of IARC Monographs Volumes 1 to 42, IARC Monogr Eval Carcinog Risk Man Suppl 7. Lyon, France 1987

  • IPCS International Program on Chemical Safety Selected Non-Heterocyclic Polycyclic Aromatic Hydrocarbons, Environmental Health Criteria 202. WHO (World Health Organization), Geneva 1998

  • Kleinbaum DG Kupper LL Muller KM Applied Regression Analysis and Other Multivariable Methods 2nd EdPWS-KENT Publishing, Boston 1988

  • Lighty JS Veranth JM Sarofim AF Combustion aerosols: factors governing their size and composition and implications to human health, J Air Waste Manage Assoc (2000) 50(9): 1565–1622

    Article  CAS  Google Scholar 

  • Mackay D Hickie B Mass balance model of source apportionment, transport and fate of PAHs in Lac Saint Louis, Quebec, Chemosphere (2000) 41(5): 681–692

    Article  CAS  Google Scholar 

  • Menichini E Urban air pollution by polycyclic aromatic hydrocarbons: levels and sources of variability, Sci Total Environ (1992) 116: 109–135

    Article  CAS  Google Scholar 

  • Nisbet ICT LaGoy PK Toxic equivalency factors (TEFs) for polycyclic aromatic hydrocarbons (PAH), Regul Toxicol Pharmacol (1992) 16: 290–300

    Article  CAS  Google Scholar 

  • Petry T Schmid P Schlatter C The use of toxic equivalency factors in assessing occupational and environmental health risks associated with exposure to airborne mixtures of polycyclic aromatic hydrocarbons (PAH), Chemosphere (1996) 32: 639–684

    Article  CAS  Google Scholar 

  • Pott F Pyrolyseabgase, Profile von polycyclischen aromatischen Kohlenwasserstoffen und Lungenkrebsrisiko-Daten und Bewertung, Staub-Reinhalt Luft (1985) 45: 369–379

    CAS  Google Scholar 

  • Prinz B Stratmann H Anwendungsmöglichkeiten der Faktorenanalyse bei Immissionsuntersuchungen, Staub-Reinhalt Luft (1968) 28: 25–30

    Google Scholar 

  • United States Environmental Protection Agency (USEPA). Provisional Guidance for Quantitative Risk Assessment for Polycyclic Aromatic Hydrocarbons (1993) EPA/600/R-93/089

  • VDI Guideline 3875 Outdoor-air pollution measurement. Indoor air pollution measurement. Measurement of polycyclic aromatic hydrocarbons (PAH). Gas chromatographic determination. Sheet 1, VDI (1996)

  • World Health Organization (WHO) Air quality guidelines for Europe. WHO regional publications European series, no. 23WHO Regional Office for Europe, Copenhagen 1987

  • World Health Organization (WHO) Updating and Revision of the Air Quality Guidelines for Europe, Brussels, Belgium, October 2–6 (1995)

  • World Health Organization (WHO) Guidelines for drinking-water quality, Addendum to Volume 2 “Health criteria and other supporting information” 1998 WHO/EOS/98.1

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Acknowledgements

The authors thank H. Blunck and M. Wessel for their technical assistance and the anonymous reviewers for their valuable suggestions.

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  1. Department of Work, Epidemiology Working Group, Health and Social Affairs and Institute for Mathematics and Computational Sciences in Medicine, Winterhuder Weg 29, Hamburg, D-22085, Germany

    REGINA FERTMANN, IRENE TESSERAUX, MICHAEL SCHÜMANN & HERMANN NEUS

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  1. REGINA FERTMANN
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  2. IRENE TESSERAUX
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  3. MICHAEL SCHÜMANN
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  4. HERMANN NEUS
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Correspondence to REGINA FERTMANN.

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FERTMANN, R., TESSERAUX, I., SCHÜMANN, M. et al. Evaluation of ambient air concentrations of polycyclic aromatic hydrocarbons in Germany from 1990 to 1998. J Expo Sci Environ Epidemiol 12, 115–123 (2002). https://doi.org/10.1038/sj.jea.7500206

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