Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

Nanoparticle assemblies

Interfaces behaving well

Interfaces between gold nanoparticle films and semiconductor substrates are found to behave like nearly ideal Schottky diodes. Moreover, the detailed electronic structure of the interfaces can be tuned by electrochemical charge-transfer.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Electrostatics of a layer of hexanethiol-coated gold particles on an InP substrate.

References

  1. Menard, E. et al. Chem. Rev. 107, 1117–1160 (2007).

    Article  CAS  Google Scholar 

  2. Boettcher, S. W. et al. Nature Mater. 6, 592–596 (2007).

    Article  CAS  Google Scholar 

  3. Chen, S. et al. Science 280, 2098–2101 (1998).

    Article  CAS  Google Scholar 

  4. Ding, Z. F. et al. Science 296, 1293–1297 (2002).

    Article  CAS  Google Scholar 

  5. Pietron, J. J., Hicks, J. F. & Murray, R. W. J. Am. Chem. Soc. 121, 5565–5570 (1999).

    Article  CAS  Google Scholar 

  6. Mönch, W. Electronic Properties of Semiconductor Interfaces (Springer, New York, 2004).

    Book  Google Scholar 

  7. Louie, S. G. & Cohen, M. L. Phys. Rev. B 13, 2461–2469 (1976).

    Article  CAS  Google Scholar 

  8. Sailor, M. J., Klavetter, F. L., Grubbs, R. H. & Lewis, N. S. Nature 346, 155–157 (1990).

    Article  CAS  Google Scholar 

  9. Yu, D., Wang, C. & Guyot-Sionnest, P. Science 300, 1277–1280 (2003).

    Article  CAS  Google Scholar 

  10. Roest, A. L., Kelly, J. J., Vanmaekelbergh, D. & Meulenkamp, E. A. Phys. Rev. Lett. 89, 036801 (2002).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Korgel, B. Interfaces behaving well. Nature Mater 6, 551–552 (2007). https://doi.org/10.1038/nmat1969

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1038/nmat1969

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing