In nature, a manganese catalyst is used for photosynthetic water oxidation, but efforts to develop artificial manganese-based counterparts have been hampered by the lability of manganese complexes. By using a bulky and hydrophilic ligand, a water-soluble Mn12 complex is found to be a stable and efficient water oxidation electrocatalyst.
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Brudvig, G.W. Catalysing water oxidation using nature’s metal. Nat Catal 1, 10–11 (2018). https://doi.org/10.1038/s41929-017-0013-1
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DOI: https://doi.org/10.1038/s41929-017-0013-1