Introduction

Pore volume compressibility (PVC) of porous media is a key parameter for characterizing coupled fluid transport and stress in reservoir rock1,2,3,4,5,6,7,8. PVC is of particular interest to the petroleum industry, especially for elastic energy evaluation, design, drilling and completion of wells, production forecasts, and material balance studies2,9,10,11,12,13. The earthquake seismology community also relies on PVC assessments for analysis of induced seismicity potential14,15.

For a porous media with pore volume Vp, the PVC of porous media cp may be determined as13,14,15,16,17,18,19,20:

$${c}_{p}=\frac{1}{{V}_{p}}\frac{\partial {V}_{p}}{\partial {p}_{p}}=-\,\frac{1}{{V}_{p}}\frac{\partial {V}_{p}}{\partial {p}_{eff}}$$
(1)

where cp represents the pore volume compressibility (MPa−1), Vp represents the pore volume (cm3), pp represents the pore pressure (MPa), and peff represents the effective stress (MPa).

In general, there are three traditional approaches to evaluate PVC including laboratory tests16,17,18,19,20,21,22,23,24,25,26, numerical methods27,28, and theory-based evaluation methods20,29,30,31,32. Probably the most common method is laboratory experimental testing, which may be classified into direct measurement methods and indirect measurement methods. In the specific content of the research described in this paper, relevant laboratory test methods, together with their characteristics, are summarized in Table 1.

Table 1 Laboratory experiment methods for pore volume compressibility.

The volume methods20,21,22,23,33,34 are probably the most commonly used measurement techniques to determine PVC. However, as stated in the literature6,13,33,34, during the experiments, the systematic errors resulting from deformation of pressurized parts (such as micro interstice between the sample and the sleeve in the core holder, core holder itself, connection pipes, etc.) exist and will affect the results. For example, according to some researchers6, the permeability difference between the first and second measurements in confining pressure loading-unloading processes varied much. Tarokh A.34 and Asaei H.33 also pointed out that the necessity of system calibration during the undrained and drained volumetric measurement tests. Specifically, the changes in loading/unloading process of confining pressure and pore pressure/effective stress during the tests lead to the change in the shape of the testing system (sleeve, core holder, pipe and other accessories) which make an extra change of volume especially for the jacketed drained tests. Physically speaking, this fluid volume change may cause a negative effect on the PVC of the porous media determination and increase the value of PVC. Although some researchers6,33,34 suggested using the systematic calibration tests to reduce this measurement error, the tests may make the volumetric measurement test process more time-consuming and costly. Thus, the test results of the volumetric method are usually costly and sometimes over-estimated especially without proper systematic calibrations. Nevertheless, it is worth noting that the repetitive stress treatment will also lead to changes in the pore structure of porous media. As an alternative direct measurement method, mercury intrusion method19 can be used to measure the PVC of porous media accurately, which eliminates the effects of micro interstice by avoiding using core holder. It is generally believed that, during the mercury intrusion porosimetry (MIP) measurements, one can easily observe the compression of samples as mercury intrusion pressure increases. The compression volume of porous media is the difference between the change of the mercury volume and the change of the pore filling volume (i.e., \(\Delta {V}_{compression}=\Delta {V}_{mercury}-\Delta {V}_{pore-filling}\)). Guo et al.19 conducted MIP tests on cylindrical coal samples with the diameter of 25 mm and the length of 50 mm, which were extracted from the middle of the coal blocks. And they crushed remaining blocks for N2 adsorption analyses. Results from MIP tests19 suggested there existed a linear relation between the mercury volume and intrusion pressure change when the pressure ranged from 7.35 MPa to 32.2 MPa (i.e., the ratio of \(\Delta {V}_{mercury}\) and Δp is a constant). Then, after determining the value of \(\Delta {V}_{pore-filling}\) with N2 adsorption analysis, they estimated the value of \(\Delta {V}_{mercury}/\Delta p\). Finally, the PVC of the coal matrix was determined by dividing \(\Delta {V}_{mercury}/\Delta p\) by the matrix volume ΔVm. Besides the direct measurement methods19,20,21,22,23, many indirect measurement methods (e.g., sonic velocity method24 and permeability test method25,26) have been used for PVC determination. More details about the sonic velocity method and permeability test method can be found in the literature24,25,26.

By and large, the experiments are costly, and the test results are usually affected by experimental error. Due to the discrepancies in physical properties of core samples and experimental methods, there are many inconsistencies in the tests’ results. As an alternative, some effective numerical methods have been proposed to simulate fluid flow in reservoir rocks, and coupling PVC is important for such27,28. However, numerical methods demand computationally-intensive calculations and typically predicted results are subject to significant uncertainties, especially as the ones induced by numerical dispersion29, as well as other similar constraints29,30. Theoretical methods for assessment of PVC may be classified into empirical models20,21,31,32, analytic models2,13 and other complex models35,36,37. Hall21, Horn31 and Jalalh32 used empirical correlations to predict PVC. Based on matching experimental data of 12 samples (i.e., 5 sandstones and 7 limestones) with the porosity ranging from 2% to 26%, Hall21 derived the empirical correlation of PVC. As one of the earliest and primary formula, Hall’s correlation has been widely used in petroleum engineering. Newman20 compared the PVC data of 256 samples with porosity ranging from 1% to 35% (e.g., 197 sandstone samples and 59 limestone samples) with that from Hall’s correlation and found PVC predicted from Hall’s correlation was in poor agreement with the experimental data. Newman20 stated that PVC of various types of rocks with a certain porosity varied widely. In addition, Jalalh32 suggested that Hall’s correlation should be used with caution. Horn31 proposed the correlation of PVC for consolidated carbonates. However, the predicted results from Horn’s model were PVC of porous media with different lithologies under 75% of the lithostatic pressure. To avoid using the compilation published dataset (e.g., initial porosity and PVC) of rocks with various lithologies, Jalalh32 proposed a correlation for PVC prediction of carbonate rocks. Although the above correlations21,22,23 to some extent, can be applied to predict PVC of porous media, these correlations contain empirical parameters, which have no clear physical meaning and vary with reservoirs. Recently, Li et al.2,13 proposed an analytical model based on porosity and rock lithology parameters to calculate the PVC of the reservoir rock. Besides the empirical models and analytic models, some scholars also calculated the PVC using other complex models. Khatchikian35 analyzed the PVC of core samples using the Gassman equation, in which parameters were evaluated via geophysical log analysis. Poston and Chen36 and Yildiz37 analyzed rock compressibility with material balance and production data.

All of the above studies convince us that, limited by the complex pore structure, relevant theoretical methods for predicting PVC are very scarce. What’s more, some research results from different theoretical models are inconsistent with each other. For example, the PVC predicted by Li’s model is quite different from the values determined by the correlation proposed by Hall21. Specifically, Li’s model suggested that the larger the porosity is, the larger that PVC will be, which is a contrast to the conclusion from other studies6,21,32 that indicated a greater PVC corresponds to a reduced porosity. Additionally, Li et al.2,13 stated that the positive correlation between PVC and initial porosity was validated by the experiments conducted by de Oliveira et al.18 and Guo et al.19. However, after careful examination, we find that the results from de Oliveira et al.18 cannot validate Li’s model. The main reason is that the curve of PVC versus porosity was plotted at different pressure stages for each core, hence the results are not the same as those from Li et al.2,13. Furthermore, results from Guo et al.19 suggest that the PVC of porous media is affected by several factors, such as the initial porosity, moisture content, and macerals, etc. Though Guo et al.19 found the PVC of medium-volatile bituminous (mvb) and low-volatile bituminou (lvb) coals exhibited a positive correlation to initial porosity, they also found there was no correlation between the PVC and porosity for the high-volatile A bituminous (hvAb) coals. Moreover, Li’s model was based on the assumption that porosity is constant during deformation, which is questionable. In most cases, PVC is not just related to porosity, but also affected by other pore structure parameters29,30,38. To the best of our knowledge, previous researches did not relate the full complement of pore structure parameters to PVC, and the fundamental controls on PVC are not yet definitive.

As stated in the literatures, the interspaces in most of porous media have fractal characteristics39,40,41,42,43,44,45. Since Mandelbrot firstly introduced the concept of the fractal to describe self-similarity of fractal objects39, many studies have been conducted to study the fractal feature of porous media40,41,42,43,44,45. Many scholars have found and suggested that fractal geometry could be applied to well characterize the complex porous structure of porous media. As a result, we take the microstructure of porous media into account and derive an analytical solution to predict PVC, based on fractal theory. Compared with the previous studies, this new model doesn’t contain empirical constants. Furthermore, it can help to reduce the uncertainty in flow through porous media and obtain data with high accuracy. As the outline of this work, the analytical model for PVC is provided in the following section. Then, the results are analyzed, followed by the discussions of the derived model. Finally, the conclusions are presented.

Methods

Theoretical model for PVC

As suggested by decades of literature, the pore structure of reservoir rocks can be well described and quantified by fractal approach39,40,41,42,43,44,45. For the sake of simplicity, the cross-sectional shapes of pores in porous media are described by circles. Meanwhile, besides assuming capillary radius does not change in the direction of flow, Euclidean dimension should be assigned as 2 in this work. Then, with a fractal approach, the equations for pore surface area at zero stress Ap0 (μm2) and pore volume before deformation Vp0 (μm3) are29,44,45:

$$\{\begin{array}{rcl}{A}_{p0} & = & \frac{\pi {r}_{{\max }}^{{D}_{f0}}{D}_{f0}}{2-{D}_{f0}}({r}_{{\max }\,0}^{2-{D}_{f0}}-{r}_{{\min }\,0}^{2-{D}_{f0}})\\ {V}_{p0} & = & \frac{4\pi {r}_{{\max }}^{{D}_{f0}}{D}_{f0}}{3(3-{D}_{f0})}({r}_{{\max }\,0}^{3-{D}_{f0}}-{r}_{{\min }\,0}^{3-{D}_{f0}})\end{array}$$
(2)

where rmax0 represents the initial maximum pore radius (μm), Df0 is the initial pore fractal dimension (dimensionless), rmin0 represents the initial minimum pore radius (μm). The correlation of Df0 and the initial porosity \({\phi }_{0}\) (dimensionless) can be expressed as27,43:

$${\phi }_{0}={({r}_{{\min }0}/{r}_{{\max }0})}^{2-{D}_{f0}}$$
(3)

Affected by effective stress, the pore structure of porous media will change, and Eq. 2 may be rewritten as29,43:

$$\{\begin{array}{rcl}{A}_{p} & = & \frac{\pi {r}_{{\max }}^{{D}_{f}}{D}_{f}}{2-{D}_{f}}({r}_{{\max }}^{2-{D}_{f}}-{r}_{{\min }}^{2-{D}_{f}})\\ {V}_{p} & = & \frac{4\pi {r}_{{\max }}^{{D}_{f}}{D}_{f}}{3(3-{D}_{f})}({r}_{{\max }}^{3-{D}_{f}}-{r}_{{\min }}^{3-{D}_{f}})\end{array}$$
(4)

where Ap represents the pore surface area (μm2), Vp represents the pore volume (μm3), rmax represents the maximum pore radius (μm), Df is the fractal dimension of pore after deformation (dimensionless), rmin represents the minimum pore radius (μm).

Assume that the specific surface area of porous media remains constant as effective stress increases, the following expression can be obtained as29,46,47:

$$\frac{{A}_{p0}}{{V}_{p0}}=\frac{3(3-{D}_{f0})}{4(2-{D}_{f0})}\frac{({r}_{{\max }0}^{2-{D}_{f0}}-{r}_{{\min }0}^{2-{D}_{f0}})}{({r}_{{\max }0}^{3-{D}_{f0}}-{r}_{{\min }0}^{3-{D}_{f0}})}=\frac{{A}_{p}}{{V}_{p}}=\frac{3(3-{D}_{f})}{4(2-{D}_{f})}\frac{({r}_{{\max }}^{2-{D}_{f}}-{r}_{{\min }}^{2-{D}_{f}})}{({r}_{{\max }}^{3-{D}_{f}}-{r}_{{\min }}^{3-{D}_{f}})}$$
(5)

By solving Eq. 5 for Df, the stress-dependent fractal dimension may be written as29,47:

$${D}_{f}=2-\frac{(2-{D}_{f0}){r}_{{\max }0}}{(3-{D}_{f0}){r}_{{\max }}-(2-{D}_{f0}){r}_{{\max }0}}$$
(6)

Combining Eqs 3 and 6, the stress-dependent porosity \(\phi \) (dimensionless) is:

$$\phi ={({r}_{{\min }}/{r}_{{\max }})}^{\tfrac{(2-{D}_{f0}){r}_{{\max }0}}{(3-{D}_{f0}){r}_{{\max }}-(2-{D}_{f0}){r}_{{\max }0}}}$$
(7)

As discussed in a previous study29, the relationship between the stress-dependent equivalent pore radius r (μm) and effective stress peff is:

$$r={r}_{0}\{1-4{[\frac{3\pi (1-{v}^{2}){p}_{eff}}{4E}]}^{\beta }\}$$
(8)

where r0 is the equivalent radius before deformation (μm), β is the power law index (dimensionless), E represents the rock elastic modulus (GPa), and ν represents the Poisson’s ratio (dimensionless).

Based on Eq. 8, the following equation is:

$$\{\begin{array}{rcl}{r}_{{\max }} & = & {r}_{{\max }0}\{1-4{[\frac{3\pi (1-{v}^{2}){p}_{eff}}{4E}]}^{\beta }\}\\ {r}_{{\min }} & = & {r}_{{\min }0}\{1-4{[\frac{3\pi (1-{v}^{2}){p}_{eff}}{4E}]}^{\beta }\}\end{array}$$
(9)

Substituting Eq. 9 into Eq. 7, the stress-dependent porosity \(\phi \) may be rewritten as:

$$\phi ={({r}_{{\min }0}/{r}_{{\max }0})}^{\tfrac{(2-{D}_{f0}){r}_{{\max }0}}{(3-{D}_{f0}){r}_{{\max }}-(2-{D}_{f0}){r}_{{\max }0}}}$$
(10)

Based on Eq. 1, the PVC cp may be defined as13:

$${c}_{p}=-\,\frac{1}{{V}_{p}}\frac{\partial {V}_{p}}{\partial {p}_{eff}}=-\,\frac{1}{\phi }\frac{\partial \phi }{\partial {p}_{eff}}$$
(11)

Subsequently, the porosity correlation may be obtained through the integration of Eq. 1120,32,38 as follows:

$$\phi ={\phi }_{0}{e}^{-{c}_{p}{p}_{eff}}$$
(12)

Combining Eqs 10 and 12, the resulting expression relating porosity and effective stress is:

$$\mathrm{ln}\,(\frac{{\phi }_{0}}{\phi })=\frac{({r}_{{\max }0}-{r}_{{\max }})(2-{D}_{f0})(3-{D}_{f0})}{[(3-{D}_{f0}){r}_{{\max }}-(2-{D}_{f0}){r}_{{\max }0}]}\,\mathrm{ln}\,(\frac{{r}_{{\max }0}}{{r}_{{\min }0}})={c}_{p}{p}_{eff}$$
(13)

This relationship between \(\mathrm{ln}({\phi }_{0}/\phi )\) and peff is linear, and the slope of the straight line represents PVC. By plotting the curve of \(\mathrm{ln}({\phi }_{0}/\phi )\) and peff, an estimate of PVC of porous media may be estimated with simple linear regression.

Workflow of PVC determination

According to our proposed model, the suggested workflow for PVC determination may be summarized as follows:

Step 1: Based on the initial average porosity \({\phi }_{0}\) and initial average permeability K0 (μm2) of a porous medium, pore structural parameters, such as rmax0, rmin0, and the initial fractal dimension of pore Df0, may be determined using Eqs 3, 14 and 15 from the literature29,

$${K}_{0}=\frac{{2}^{{D}_{T0}}\pi {D}_{f0}{r}_{{\max }0}^{{D}_{f0}}}{16{A}_{0}{L}_{0}^{{D}_{T0}-1}}\frac{{r}_{{\max }0}^{3+{D}_{T0}-{D}_{f0}}-{r}_{c0}^{3+{D}_{T0}-{D}_{f0}}}{3+{D}_{T0}-{D}_{f0}}$$
(14)
$$\{\begin{array}{rcl}{A}_{0} & = & \tfrac{{A}_{p0}}{{\phi }_{0}}=\tfrac{\pi {r}_{{\max }0}^{2}{D}_{f0}}{2-{D}_{f0}}(\tfrac{{r}_{{\max }0}^{2-{D}_{f0}}}{{r}_{{\min }0}^{2-{D}_{f0}}}-1)\\ {L}_{0} & = & \sqrt{{A}_{0}}={r}_{{\max }0}\sqrt{\tfrac{\pi {D}_{f0}}{2-{D}_{f0}}(\tfrac{{r}_{{\max }0}^{2-{D}_{f0}}}{{r}_{{\min }0}^{2-{D}_{f0}}}-1)}\\ {D}_{T0} & = & 1+\tfrac{\mathrm{ln}\,\{\tfrac{1}{2}[1+\tfrac{1}{2}\sqrt{1-{({r}_{{\min }0}/{r}_{{\max }0})}^{2-{D}_{f0}}}+\tfrac{\sqrt{{[1-\sqrt{1-{({r}_{{\min }0}/{r}_{{\max }0})}^{2-{D}_{f0}}}]}^{2}+\tfrac{1}{4}[1-{({r}_{{\min }0}/{r}_{{\max }0})}^{2-{D}_{f0}}]}}{1-\sqrt{1-{({r}_{{\min }0}/{r}_{{\max }0})}^{2-{D}_{f}}}}]\}}{\mathrm{ln}\,[\tfrac{{D}_{f0}-1}{\sqrt{{D}_{f0}}}\sqrt{\tfrac{1-{\phi }_{0}}{4{\phi }_{0}}\tfrac{\pi }{2-{D}_{f0}}}\tfrac{{r}_{{\max }0}}{{r}_{{\min }0}}]}\end{array}$$
(15)

where A0 is the initial cross-sectional area of porous media (μm2). L0 is the initial capillary representative length (μm). DT0 is the initial tortuosity fractal dimension (dimensionless).

Step 2: Select parameters E, v, and the values of effective stress peff, and then calculate the parameters rmax0 and rmin0 using Eq. 9. Then, the stress-dependent porosity \(\phi \) may be determined with Eq. 10;

Step 3: Based on Eq. 13 and its plot, the PVC cp may be estimated using linear regression.

Results

Model validation

As previously discussed, reports using analytical methods to study PVC are scarce48. Some typical correlations for PVC, together with their characteristics, are summarized in Table 2.

Table 2 Some correlations for PVC.

Figure 1 compares the measured PVC48 and that predicted by our derived model and other models in Table 2 (e.g. Hall’s model21, Horne’s model31 and Jalalh’s model32). In the experiment of da Silva Jr G.P. et al.48, the PVC tests were conducted on clean and dry rock samples with K0 of 3.5 × 10−3 μm2 and \({\phi }_{0}\) of 18.8%. In our proposed model, the parameter E assigned was 18 GPa, ν assigned was 0.18 and β assigned was 1.05. Besides, to ensure the parameter K0 is 3.5 × 10−3 μm2, the critical radius for irreducible water saturation assigned is 0, the initial porosity 18.8%, with the values of initial maximum and minimum radii at 1.36 μm and 0.0016 μm, respectively. Figure 1 reveals that the predicted PVC of our derived model is consistent with that determined by experimental data48, and our predictions are more consistent with experimental data than those predicted by previous models.

Figure 1
figure 1

The test data48 versus PVC predicted from different models.

Figures 2 and 3 compares the PVC values predicted by the derived model with test data24. In the experiment of He et al.24, the PVC tests were carried out on six rock samples with a permeability test method and a triaxial stress method. The parameters applied in the calculations are summarized in Table 3. Since the relative error is less than 6.0%, results (Figs 2 and 3) show that the predicted results of our model are in agreement with the corresponding test data24. Results (see Fig. 2) also demonstrate that the PVC is not only related to \({\phi }_{0}\), but also is affected by other pore structure parameters. For example, the PVC of Core 1 with an initial porosity 4.4% is less than that of Core 4 with initial porosity 3.5%. However, the PVC of Core 4 with initial porosity 3.5% is larger than that of Core 3 with initial porosity 3.2%. Thus, the effects of pore structure parameters on PVC should probably be considered to elucidate primary controls on it.

Figure 2
figure 2

Experimental data24 versus the predictions: the results from different methods.

Figure 3
figure 3

Experimental data24 versus the predictions: the relative error.

Table 3 Parameters applied in the proposed model.

Figure 4 presents the comparison between the predictions of PVC and experimental data reported in the work of Guo et al.19. In the experiments19, PVC tests were conducted on 21 coal samples with an initial maximum pore radius of 0.1 μm. In the calculation, the rmax0 was assigned as 0.1 μm, the rmin0 was assigned with 0.001 μm, the E was assigned with 52 GPa, and the ν was assigned as 0.25. Results (Fig. 4) suggest that the predictions are consistent with the measured experimental data19. Additionally, simulated results also indicate that the relationship between initial porosity and PVC is not monotonic, suggesting that PVC is correlated not only to \({\phi }_{0}\), but also to other pore structure parameters.

Figure 4
figure 4

Experimental data19 versus the predicted results.

Parameter influence

Figure 5 presents PVC versus the power law index β. In the calculation, the rmax0 was 1 μm, the rmin0 was 0.001 μm, the initial porosity \({\phi }_{0}\) assigned was 9%, the rock Poisson’s ratio ν assigned was 0.17, and the rock elastic modulus E assigned was 40 GPa. Figure 5 shows that PVC monotonically decreases as power law index β increases46.

Figure 5
figure 5

The PVC versus power law index β.

Figure 6 shows the PVC variation with different rock elastic modulus. For the calculations necessary to assemble this plot, the rmax0 was 1 μm, the rmin0 was 0.001 μm, the initial porosity \({\phi }_{0}\) assigned was 23%, parameter ν was 0.17 and β was 1.3. Figure 6 suggests that the PVC decreases as the parameter E increases. The main reason for this is that the larger E corresponds to the smaller contact surface radius, which leads to the smaller PVC. As a result, reservoir rocks with relative “softer” lithology can yield higher compressibility13.

Figure 6
figure 6

The PVC versus rock elastic modulus.

Figure 7 demonstrates the PVC versus the parameter rmin0/rmax0. In the calculation, the initial porosity \({\phi }_{0}\) assigned was 9%, parameter E assigned was 20 GPa, ν assigned was 0.17, and β assigned was 1.3. PVC increases with rmin0/rmax0 (Fig. 7), indicating that smaller pores exhibit lower stress sensitivity than larger pores. Increases of parameter rmin0/rmax0 (increases in the initial minimum radius rmin0) lead to increases of PVC.

Figure 7
figure 7

The PVC versus the parameter rmin0/rmax0.

Discussions

Effect of pore aspect ratio on PVC

It’s well known that the real cross-sectional shapes of pores are complex and highly irregular9. Zimmerman9 suggested that the influence of pore aspect ratio (i.e., the ratio of pore’s height to its width) on PVC of porous media was significant, which could not be neglected. As stated in the literature9, the PVC of an elliptical tubular pore cpe is

$${c}_{pe}={c}_{pr}(\frac{\alpha }{2}+\frac{1}{2\alpha })$$
(16)

where cpr represents the PVC of the circular tubular pore, whose area is the same as that of the elliptical tubular pore (MPa−1), and α is the pore aspect ratio. Equation 16 shows that, when \(\alpha =1\), cpe is equal to cpr, which is expected. Moreover, cpe is impossible less than cpr, which illustrates that, when other properties are the same, an elliptical tubular pore is easier to be compressed than a circular tubular pore.

Based on Eqs 9 and 16, the equivalent pore radius of elliptical tubular pores can be modified as

$$\{\begin{array}{rcl}{r}_{{maxe}} & = & {r}_{{\max }0}-({r}_{{\max }0}-{r}_{{\max }})\sqrt{(\frac{{\alpha }_{{\max }}}{2}+\frac{1}{2{\alpha }_{{\max }}})}\\ {r}_{{mine}} & = & {r}_{{\min }0}-({r}_{{\min }0}-{r}_{{\min }})\sqrt{(\frac{{\alpha }_{{\min }}}{2}+\frac{1}{2{\alpha }_{{\min }}})}\end{array}$$
(17)

where rmaxe represents the equivalent maximum pore radius (μm), rmine represents the equivalent minimum pore radius (μm), αmax is the pore aspect ratio of the maximum pore, and αmin is the pore aspect ratio of the minimum pore. For the sake of simplicity, the values of pore aspect ratio of each elliptical pore are assumed to be equal. Then, Eq. 17 can be rewritten as

$$\{\begin{array}{rcl}{r}_{{maxe}} & = & {r}_{{\max }0}-({r}_{{\max }0}-{r}_{{\max }})\sqrt{(\frac{{\alpha }_{av}}{2}+\frac{1}{2{\alpha }_{av}})}\\ {r}_{{mine}} & = & {r}_{{\min }0}-({r}_{{\min }0}-{r}_{{\min }})\sqrt{(\frac{{\alpha }_{av}}{2}+\frac{1}{2{\alpha }_{av}})}\end{array}$$
(18)

where αav is the average pore aspect ratio of the elliptical pores in the porous media.

Substituting Eq. 18 into Eqs 7 and 10 is rewritten as

$$\phi ={({r}_{{\min }0}/{r}_{{\max }0})}^{\tfrac{(2-{D}_{f0}){r}_{{\max }0}}{(3-{D}_{f0}){r}_{{maxe}}-(2-{D}_{f0}){r}_{{\max }0}}}$$
(19)

Then, with the same method stated above, PVC of porous media accounts for pore aspect ratio can be determined. Figure 8 demonstrates the PVC versus the parameter αav. Results (Fig. 8) suggest that porous media with more elliptical pores (e.g., prolate pores and oblate pores) has a larger value of PVC. Similar results were also shown in the literature9.

Figure 8
figure 8

The PVC versus the parameter αav.

Advantages and limitations of the derived model

The analytical model lays a theoretical foundation for predicting the PVC of porous media. With this new analytical solution,the uncertainty in flow through porous media could be reduced and higher data accuracy could be obtained. Moreover, it can be applied to estimate more accurate microstructure parameters of porous media using inverse modeling. However, our derived model is limited to matrix core samples, as it ignores the deformation of joints and fractures. And we are trying to study the PVC of fractured porous media. In addition, the pore aspect ratio distribution of the real pores in porous media is neglected, which may result in the calculation errors.

Conclusions

A novel analytical model to predict porous media PVC is derived. Predictions deduced from the derived analytical solution agree well with the test results. And the predicted PVC values are robust. Followings are the main conclusions:

  1. 1.

    Porous media PVC is affected by its porous media microstructural parameters and rock lithology. When all the other parameters are fixed, there is a definitive negative correlation between PVC and initial porosity. However, if all the other parameters are inconstant, the relationship between initial porosity and PVC is not monotonic. The blind application of pore compressibility-initial porosity relationships may lead to excessive uncertainty in any analyses based on those relationships. Thus, the specific pore structure parameters for various types of rocks need to be defined through further study to improve the accuracy of the PVC prediction, and in turn production prediction.

  2. 2.

    Porous media with relative “softer” lithology may yield larger PVC. In addition, a smaller value of PVC corresponds to rougher pore surfaces. As rock lithology (e.g., Poisson’s ratio, and elastic modulus) is affected by the rock physical properties (e.g., mineral component, organic matter distribution, and clay content), when making a prediction about PVC, the rock physical properties should be considered.

  3. 3.

    The new analytical model, considering porous media microstructure and rock lithology, is useful for PVC prediction of porous media. It can help to reduce the uncertainty in flow through porous media. What’s more, besides providing theoretical foundations for quantifying PVC of porous media, this new analytical model could also be applied to estimate pore structure parameters of porous media using inverse modeling.