Abstract
Herein, we suggest a methodology for the fabrication of well-defined metallic nanoporous spheres with single gyroid (SG) structure by simply using self-assembled diblock copolymer with double gyroid (DG) structure as a template for electroless plating. Note that owing to the consideration of thermodynamic stability, the self-assembly of diblock copolymers gives rise to a DG phase instead of an SG phase. By controlling the nucleus density for the reduction of Pd ions within the diblock copolymer template, SG-structured Ni can be easily fabricated through the nucleation and growth processes. Consequently, nanoporous Ni spheres with uniform pore sizes and high specific surface areas can be fabricated. Moreover, nanoporous Ni spheres with controlled microscale particle sizes can thus be obtained by controlling the reduction time for the growth of Ni, which enables the feasibility of recyclability via magnetic fields. The combination of structural and morphological characteristics of the fabricated nanoporous Ni spheres make them appealing for use in a wide variety of applications, such as high-efficiency and well selectivity hydrogenation catalysts with recyclability due to their narrow pore size distributions, high specific surface areas, 3D curved surfaces, and controlled microscale particle sizes.
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Introduction
Nanostructural and morphological designs of metallic materials have drawn much attention because of their effectiveness in tuning electronic, optical, and magnetic properties1,2,3,4,5,6,7,8,9,10. In particular, the synthesis of nanoporous metals with controlled pore size and shape has become a main goal of extensive research on catalytic materials in recent years11,12,13. It is noted that highly active low-coordinated atoms can be acquired from the curved surfaces of interconnected networks, which serve as excellent catalytic sites for chemical reactions14,15,16. Nanoporous metals fabricated with manufacturing approaches such as dealloying usually appear as two-dimensional (2D) sheet-like structures1,17,18. It is essential to determine how to increase both the surface area to mass ratio and the density of catalytic sites of nanoporous metals to boost their surface activity performances over those of conventional 2D sheets. As a result, the fabrication of three-dimensional (3D) porous metals, particularly with nanoscale network textures, is in strong demand because of their large specific surface areas from the reduced pore sizes and self-supporting characteristics with low densities (i.e., lower required mass for equivalent catalytic efficiency). Therefore, the fabrication of 3D network catalysts has been dedicatedly conducted19. Note that high-performance catalysts are also recognized by their recyclability in addition to their catalytic efficiency. To recycle metallic catalysts, a filtering process is usually required to separate the metallic catalysts from the products. However, the filtering process is one of the most expensive procedures in industrial fabrication. One solution is to fabricate microscale metallic nanoporous spheres (MNSs) with magnetic properties for recycling purposes. Solutions with well-dispersed metallic spheres can be simply achieved by shearing due to the micrometer size of the spheres, which serves as the smallest size with saturation magnetization close to bulk20, gives the required dispersion for the intended reactions and provides feasibility for the collection of metallic catalysts after the reactions21. Although the reported properties and applications of MNSs have been promising, synthesizing monodispersed free-standing MNSs with superior catalytic performance and recyclability via a simple and cost-effective strategy remains a challenge22.
In recent decades, block copolymers (BCPs) have been extensively investigated because of their ability to self-assemble into one-dimensional (1D), 2D, and 3D periodic nanostructures with readily adjustable sizes, depending on their constituted compositions and molecular weights23. By taking advantage of the degradable characteristics of gyroid-forming BCPs, nanoporous polymers with well-ordered network textures can be prepared by the preferential removal of constituted degradable components in BCPs24,25,26,27,28,29,30,31. Because well-ordered porous polymers contain continuous nanochannels, a variety of synthetic processes have been developed by using fabricated nanoporous polymers as templates for the fabrication of well-defined nanohybrids and inorganic metals with appealing properties after removal of the polymer template32,33,34,35. Herein, we aim to suggest a facile approach for the fabrication of MNSs with network textures, which provide high porosities, controlled pore sizes, and narrow pore size distributions by exploiting nucleation and growth mechanisms for the reduction of metallic ions from templated electroless plates by using gyroid-structured templates from the self-assembly of diblock copolymers36. The self-assembled gyroid phase from diblock copolymers is a pair of gyroid networks, wherein one is right-handed and the other is left-handed, that gives a thermodynamically stable morphology. Note that well-defined metallic nanonetworks have been fabricated via templated electroless plating in our previous work; however, our previous work fabricated shifting double gyroid (DG) network with a pair of right-handed and left-handed networks, which resulted in a broadened pore size distribution after removal of the polymer template37,38. Moreover, the fix-bed type of fabricated nanonetwork-structured metallic materials hampered the catalytic performances of the intended chemical reactions in solutions, which resulted in the occurrence of catalytic poisoning and a lack of suspendability. With the use of a higher reduction potential material (i.e., Pd) as an initial nucleus for the reduction of Ni ions, it is feasible to acquire single gyroid (SG)-structured Ni from the DG-forming template. Following the growth of the reduced Ni, a well-developed SG-structured Ni sphere with controlled pore size can be successfully fabricated; this solves the pore size broadening problem that occurs in templated synthesis using DG-structured templates after removal of the template, which is caused by network shifting. Additionally, the suspendability and recyclability characteristics of their micrometer-sized spherical textures are beneficial to homogeneous catalytic reactions in chemical solutions. With a narrow pore size distribution, high specific surface area, 3D curved surface, and controlled microscale particle size (i.e., the growth size of the reduced Ni), the fabricated SG-structured Ni nanoporous sphere is an ideal candidate to serve as a high-efficiency recyclable catalyst, which is demonstrated in the catalytic hydrogenation of unsaturated organics and intended for unsaturated polymers.
Materials and methods
Materials
Polystyrene-b-poly(l-lactide) (PS-PLLA) was prepared by Atom transfer radical polymerization (ATRP) synthesis followed by ring-opening polymerization, whereas polystyrene-b-poly(dimethyl siloxane) (PS-PDMS) was prepared by anionic polymerization. As described in our previous works, PS-PLLA (molecular weight, Mn, PS = 38,100 g mol−1, Mn, PLLA = 24,700 g mol−1, Đ = 1.23, fPLLAv ≈ 0.35, where fPLLAv is the volume fraction of PLLA) and PS-PDMS (molecular weight, Mn, PS = 51,000 g mol−1, Mn, PDMS = 35,000 g mol–1, Đ = 1.03, fPDMSv ≈ 0.42, where fPDMSv is the volume fraction of PDMS) were used as materials for solution casting to fabricate PS templates with DG nanochannels. After hydrolytic treatment with a sodium hydroxide aqueous solution (2 M), PLLA block can be selectively removed, which yields DG-structured PS with interconnected nanochannels and thru-pore characteristics (Fig S1). Similar porous PS can also be obtained by using self-assembled PS-PDMS (Fig S2(a)) for selective hydrofluoric acid (HF acid) etching of the PDMS block (Fig S2(b)).
Fabrication of SG-structured MNSs via electroless plating
To fabricate Ni nanoporous spheres, electroless plating was carried out through nucleation and growth mechanisms. For nucleation, the nanoporous PS templates were soaked in a low-concentration activating solution mixed with methanol (45 mL), HCl (1 N, 5 mL), and PdCl2 (0.004 g) for several hours (3–4 h) followed by immersion in a reduction solution of hydrazinium hydroxide (5 mL) and methanol (15 mL). After nucleation, the template with the nucleus was soaked in a Ni bath (0.2 g of nickel chloride (NiCl2 · 6H2O) dissolved in a solution containing distilled water (20 mL), methanol (20 mL), hydrazinium hydroxide (85%, 2 mL), and ammonia (3.5 mL)) to grow the Ni. To obtain the free-standing SG-structured Ni nanoporous sphere, the PS/Ni gyroid-structured nanohybrids were washed with either dichloromethane or tetrahydrofuran (THF) to remove the nanoporous PS template.
Transmission electron microscopy
To acquire transmission electron microscopy (TEM) images, an SG-structured Ni nanoporous sphere in a PS template was prepared by microtomy. A JEOL JEM-2100 LaB6 transmission electron microscope was used for TEM imaging at an accelerating voltage of 200 kV.
Field-emission scanning electron microscopy
To acquire field-emission scanning electron microscopy (FESEM) images, an SG-structured Ni powder was prepared after the PS template was removed. A JEOL JSM-6700 field-emission scanning electron microscope was used for FESEM imaging at accelerating voltages of 1.5e3 keV.
In situ small-angle X-ray scattering
In situ temperature-resolved small-angle X-ray scattering (SAXS) experiments were conducted at the synchrotron X-ray beam-line X27C at the National Synchrotron Radiation Research Center in Hsinchu, Taiwan, to examine the forming Ni texture in the PS/Ni nanohybrids.
Wide-angle X-ray diffraction
Wide-angle X-ray diffraction (WAXD) was conducted to examine the crystallinity of the SG-structured Ni. As shown in Fig S3, all of the diffractions can be indexed as face-centered cubic Ni with the lattice constant a = 3.52 Å, JCPDS card no. 4-856, corresponding to the reflections from the (111), (200), (220), (311), and (222) planes. Moreover, the characteristic peaks of NiO and Ni(OH)2 were not detected, which indicates that a well-defined crystalline structure of the Ni structure can be obtained under ambient conditions from templated electroless plating without oxidation.
Demonstration of the recyclability of Ni nanoporous spheres
As demonstrated in Video S1, the Ni nanoporous spheres in powder form used for the catalytic reaction of hydrogenation were dispersed in toluene to create a solution with 50 mg Ni catalyst in 15 mL toluene as a representative condition for the reaction. The Ni catalyst powders can be effectively collected by a regular magnet, and then the dispersion of the collected Ni powders can be simply achieved by ultrasonic agitation. The collection and dispersion of the Ni powders can be easily repeated without any limitation.
Results and discussion
Synthesis and identification of DG-structured and SG-structured Ni
Figure 1 illustrates the experimental procedures for the fabrication of the MNSs in this study. As previously demonstrated by our laboratory, nanoporous PS with DG-structured nanochannels can be fabricated by either hydrolyzing self-assembled PS-PLLA or HF etching of PS-PDMS, which can then be used as templates for the fabrication of DG-structured Ni through templated electroless plating32,39,40. With a completely pore-filled Pd2+ solution within the nanochannels of the PS template, homogeneously distributed Pd nuclei can be formed using hydrazine as the reduction agent. As shown in Fig. 1a, the formation of Pd nanoparticles from the reduction of Pd ions is carried out first, and then the Pd nanoparticles can serve as nuclei for the reduction of Ni ions to give DG-structured Ni. In contrast, with a decrease in the nucleation density (i.e., the number of Pd nuclei in the template), as shown in Fig. 1b, SG-structured Ni can be fabricated due to the annihilation and growth of nickel simultaneous from neighboring nanochannels. Consequently, SG-structured Ni nanoporous spheres with controlled sphere sizes can be obtained by tuning the growth time of reduced Ni ions through the nucleation and growth processes.
Figure 2a, b show the TEM micrographs of the forming Pd nanoparticles in the PS template. As illustrated in Fig. 2a, Pd nanoparticles can be homogenously distributed in the PS template when the concentration of Pd ions in methanol is high (see below for details). In contrast, a significant reduction in the number of Pd nanoparticles can be found once the concentration of Pd ions in methanol is decreased to a certain level (see below for details); as exemplified in Fig. 2b, a single Pd nanoparticle can be observed from the viewing area. Subsequently, the reduction of the Ni ions using the Pd nanoparticles as catalytic sites can be carried out, which generates the formation of Ni network(s) through continuous growth within the gyroid-structured nanochannels. With a high density of Pd nanoparticles in the PS template, it is reasonable to expect the formation of two interdigitated networks. As shown in Fig. 2c, the [111] projection of the DG-structured PS/Ni nanohybrids can be clearly identified without staining, wherein the high mass-thickness contrast of Ni appears as the dark microdomains, whereas the PS is the bright matrix. In contrast, with a low density of Pd nanoparticles in the PS template, only one network will be formed, as evidenced from the [111] projection in which the hexagonally packing cell texture can be clearly observed (Fig. 2d). After removal of the PS template via dissolution with dichloromethane, the double-network texture of the DG-structured Ni can be clearly observed, as shown in Fig. 2e. In contrast, the single-network texture of the SG-structured Ni can be identified (Fig. 2f). Figure 2g shows the 1D SAXS profile of the fabricated DG-structured PS/Ni. On the basis of the characteristic scattering reflections at the relative q values of √6 and √8, the DG-structured PS/Ni nanohybrids (space group of Ia3d) can be identified macroscopically; the weak reflections are attributed to the strong scattering background from the forming Ni that smears the reflections from diffraction. Note that q = 4πλ−1sinθ, where 2θ is the scattering angle. The corresponding 1D SAXS profile (Fig. 2h) further confirms the observed SG-structured Ni in which the characteristic reflections for a space group of I4132 are found at the relative q values of √2, √6, √8, √12, √18, and √30. The appearances of the high-order reflections are attributed to the lower effects from scattering of the reduced Ni on the smearing of reflections. To further examine the structure of the fabricated Ni, electron tomography (3D TEM) was carried out to directly visualize the forming texture in real space. As shown in Fig S4(a), a 3D image of the SG-structured Ni in the PS matrix can be reconstructed from a set of 2D images at different tilt angles for projection (see SI for details). Fig S4(b) shows the corresponding simulated projection of the SG network.
As evidenced by the TEM observations and SAXS results, PS/Ni nanohybrids composed of SG-structured Ni in the PS template can be successfully fabricated using the template with low-density Pd nanoparticles as the nucleus to grow Ni via electroless plating. To further examine the forming Ni texture in the PS/Ni nanohybrids, in situ temperature-resolved SAXS experiments were conducted; the SG-structured PS/Ni nanohybrids were heated at a rate of 1 °C/min from 50 to 185 °C to trace the morphological evolution with a particular focus on the corresponding variations (Fig S5). There are no significant variations when the temperature is below 100 °C (i.e., the Tg of PS), and the scattering result is contributed by the PS template with a DG-structured nanochannels (at relative q values of √6 and √8) and the SG-structured Ni with a single-network texture (at relative q values of √2, √6, and √8). Interestingly, once the temperature rises above 100 °C, there are obvious changes in the reflections of √6 and √8, which experience substantial intensity reductions. When the temperature increases above 105 °C, where the PS template will be greatly softened and cause the collapse of the template texture (as evidenced by SEM observations; results not shown), the characteristic scattering reflection at the low q region (i.e., the √2 reflection) can be clearly identified from the reflections of the √6 and √8 and becomes the primary peak in terms of scattering intensity. Note that compared to the reflections of √6 and √8, the intensity of the √2 peak almost remains constant regardless of the thermal treatment. These results suggest that the thermal treatment gives rise to the softening of the PS template with DG texture, which results in the weakening of the scattering from the DG-structured PS template due to its draining from the self-supporting Ni network, while the appearance of isolated SG-structured Ni gives a characteristic scattering profile at the relative q values of √2, √6, and √8. As a result, a successful approach for the fabrication of SG-structured Ni can be achieved by simply controlling the nucleation density of Pd nanoparticles for the reduction of the Ni via templated electroless plating.
To further examine the nucleation and growth mechanism of the templated electroless plating, methanol solutions with different concentrations of Pd ions, 12, 120, 360, 600, and 840 ppm, were prepared for the reduction of the Pd ions in the PS template. Figure 3a shows the SAXS profiles of the PS/Ni nanohybrids. In contrast to the nanoporous PS, the low-q reflection at the relative q value of √2 can be easily recognized from the √6 and √8 reflections even though the concentration of Pd ions is as low as 12 ppm; this phenomenon illustrates that the scattering intensity from the forming SG-structured Ni in the PS template (Fig. 3b) is significant due to the large mass-thickness contrast of the Ni from the PS. With further increasing the Pd ion concentration (e.g., 120 ppm), the intensity of the √2 reflection can be gradually enhanced compared to those of √6 and √8; the observed variations are in agreement with suggested the nucleation and growth mechanism. Nevertheless, once the concentration of the Pd ions reaches a critical amount (e.g., 360 ppm), the intensity of the √2 reflection will be equivalent to that of √6, which indicates that the reduced Pd ions in the PS template may form the Pd nanoparticles in the neighboring nanochannels that results in the formation of DG in some regions of the template; this phenomenon is evidenced by the TEM observations (Fig. 3c). The TEM micrographs show biphasic morphologies with SG- and DG-structured Ni in the PS template at which the DG-structured Ni is marked with the red dashed circle. Subsequently, as the concentration of Pd ions increases to a certain amount (e.g., 600 ppm), a recognizable reduction in the intensities of the reflections can be found due to the significant scattering from the forming Ni that smears out the diffraction results of the ordered structure of the PS/Ni nanohybrids. With the introduction of a large number of Pd ions (e.g., 860 ppm) for reduction, it is reasonable to expect the formation of DG-structured Ni in the PS template in which the Pd clusters are homogeneously distributed in the PS matrix, which generates the DG-structured Ni in the nanohybrids, as evidenced by Fig. 3d. Namely, the formation of a well-distributed Pd nucleus in two independent networks of a DG-structured PS template gives rise to the reduced Ni ions to fill the nanochannels of the PS template completely through templated electroless plating. Consequently, due to the large scattering from the forming Ni, the scattering profiles of the nanohybrids in Fig. 3a become less identifiable. On the basis of the morphological observations examined above, it is feasible to tune the formation of SG-structured Ni from the uniformly dispersed Pd nucleus in the DG-structured PS template by controlling the concentration of Pd ions introduced, which further demonstrates that the formation of the reduced Ni is indeed conducted by the nucleation and growth mechanisms.
Controlled growth of spherical particle size with adjustable pore size
Figure 4 shows a low-magnification FESEM micrograph of an SG-structured Ni nanoporous sphere in which the SG-structured Ni network with a nanoscale uniform frame size and a microscale spherical texture can be clearly recognized after removal of the template. Moreover, a large number of micrometer-sized SG-structured Ni nanoporous spheres can be successfully obtained, which gives the potential for large-scale fabrication of Ni nanoporous spheres with micrometer-sized particles for various applications. The inset image of Fig. 4a shows a photograph of the SG-structured Ni in a brown powder form, which further demonstrates the fabrication of a great number of nanoporous Ni spheres in the powders. Figure 4b shows a high-magnification image of the fabricated Ni nanoporous sphere in which a well-ordered SG texture can be clearly identified; similar morphological results can be observed in all of the nanoporous Ni spheres fabricated above. The crystalline structure of the SG-structured Ni was identified by a WAXD experiment (Fig S3). As a result, the sphere size of the SG-structured Ni can be well-controlled through the growth process by placing the PS template, which contains a low-concentration Pd ions, in the solution for different growth times. To acquire systematic analysis on the growth of the Ni from templated electroless plating, morphological observations from SEM were conducted.
As shown in Fig. 5a–d, it is reasonable to observe the increase in the sphere size with respect to the reaction time (i.e., the growth time). The sphere size is approximately 320 nm after 3 h of reaction and gradually increases to approximately 760 nm after 7.5 h. On the basis of the statistical calculation for the average particle size from the SEM micrographs, the growth rate can be estimated; as shown in Fig. 5e (black line), a linear relationship between the particle size and the reaction time can be found when the reaction time is <7.5 h, which suggests a typical growth pattern for the growth mechanism of heterogeneous nucleation initiating from the forming Pd nucleus. However, the growth rate of the SG-structured Ni nanoporous sphere experiences a reduction once the reaction time is >7.5 h. To further understand the cause of the reduction in growth rate, a control experiment was designed by using a uniform Ni plate for electroless plating to trace the growth rate of Ni deposition for longer reaction times. A silicon wafer with a surface roughness <5 nm was coated with a smooth Ni thin film via sputtering and then immersed in the electroless plating bath for Ni deposition under the same conditions as the SG-structured Ni fabricated from templated electroless plating. The deposition rate of the Ni plate, rp (nm/h), can be calculated from the weight gain of the Ni plate before and after Ni deposition via electroless plating using the following equation: rp = ω × 107/σAt, where ω, σ, A, and t represent the weight increment (g), deposit density (g/cm3), substrate surface area (cm2), and deposition time (h), respectively. The experimental values recorded in this study were the average values of more than five measurement results. As shown in Fig. 5e (red line), the film thickness constantly increases from approximately 330 to 1180 nm as the reaction time increases from 3 to 10.5 h, which is a linear relationship that is nearly equivalent to that from templated electroless plating. However, in contrast to the templated electroless plating, there is no reduction in the growth rate for the control experiment. We speculate that the reduction in the growth rate during the templated electroless plating is attributed to the depletion of the Ni ions, while the blocking of Ni ions occurs due to the formation of Ni. To further demonstrate the feasibility of the developed platform technology, PS-PLLA or PS-PDMS with different molecular weights and volume fractions were used to prepare Ni nanoporous spheres with SG-structured textures.
The control of the lattice constant for the SG and the corresponding filling ratios of the metallic nanoporous materials are critical to the expected properties for practical applications. To further demonstrate the feasibility of the developed platform technology for the preparation of Ni nanoporous spheres with SG-structured textures, the lattice constant of the SG and the corresponding filling ratio of the nanoporous Ni DG-structured PS-PLLA or PS-PMDS with different molecular weights and volume fractions were used to induce variations in the lattice constant of the SG-structured Ni and filling ratios of the fabricated nanoporous Ni. By using PS-PLLA as an example, on the basis of the SAXS results (Fig S6), the interdomain spacing of (110)SG for SG-structured Ni was determined to be approximately 113.0 and 87.1 nm from the primary reflection (blue and black lines). The lattice constants of SG-structured Ni can be calculated as 159.8 and 123.2 nm. The filling ratios of SG-structured Ni with one single network can also be obtained as 21.0 and 17.5% from presynthesized PS templates with volume fractions of 42 and 35%. Similar to the PS-PLLA demonstrated above, the lattice constant for the PS-PDMS can be sufficiently tuned through precision synthesis (Fig S6; see SI for details).
Positron annihilation spectroscopy was used to determine the pore size distribution of the fabricated SG-structured Ni. A total of 50 mCi of 22Na was used as a positron source for the analysis. After implantation of the positron into the SG-structured Ni nanoporous spheres in powders under ambient conditions, the lifetime of the positron was detected (Fig. 6a). Within the lifetime being detected, the distribution of the longest o-Ps lifetime (Fig. 6a) was fitted to obtain the pick-off annihilation rate of o-Ps (ns−1) (λR) based on the age-momentum correlation technique combined with the selection of the 3γ annihilation located in the range of 340–490 keV analyzed by using the PATFIT program. Consequently, the pore size of the fabricated SG-structured nickel was calculated based on the following equations in which the relationship between λR and volume radius (R) was derived by Tao and co-workers and further modified to Eq. (1) to include 3γ from the o-PS annihilation to calculate pore sizes larger than 1 nm with ΔR = 16.56 nm, Ra = 0.8 nm and b = 0.5541,42. Figure 6b shows the calculated pore size distribution in which the full width at half of maximum (Dfwhm) can be as low as 3.7 ns, which indicates that the SG-structured nickel possesses a uniform pore size of approximately 22.4 nm; this result is in agreement with the observed pore size from Fig. 4, in which the pores should be well connected.
Demonstration of using SG-structured MNSs for applications
Due to its uniform nanoscale pore size, network texture, and controlled microscale sphere, the fabricated nanoporous Ni sphere is appealing for use in a wide variety of applications; herein, we aim to exploit it as a high-efficiency hydrogenation catalyst as an exemplary application. Note that Ni metal is a commonly used heterogeneous catalyst in hydrogenation processes. In heterogeneous catalytic hydrogenation processes, efficient catalysts should provide high catalytic activity and excellent recyclability. For catalytic activity, the efficiency depends closely on the specific surface area and the kinetics of the mass transport process. Ni reduction by electroless plating is known to be organized in the face-centered cubic (fcc) crystalline phase, as evidenced by the reflections of (110), (220), and (200) in WAXD (Fig S3). A tight packing of atoms in the fcc lattice makes the reactants easily absorb on the surface of Ni. Most importantly, with the well-defined SG structure containing extremely high specific surface area, it is reasonable to expect high performance on the hydrogenation reaction. Furthermore, the continuous network structure of the SG with specific curvature and uniform pore size would definitely lower the limitation for mass transport of the reactants within the nanochannels, which provides the effectiveness of the surface area inside the Ni nanoporous sphere and prevents the unnecessary blocking caused by regions with smaller pore size; moreover, such a situation might occur in DG-structured Ni due to the shifting of networks after removal of the PS template43. The catalytic activity of the SG-structured Ni nanoporous sphere was demonstrated by hydrogenation of the aromatic ring (i.e., toluene) under regular reaction conditions (60 bar and 200 °C), in which the conversion was approximately 97%; in contrast, the conversion by Raney® nickel under the same conditions was approximately 70%. The respective turnover frequencies are listed in Table 1. Accordingly, the catalytic efficiency of the fabricated SG-structured Ni porous sphere performs were better than that of the commonly used Ni catalyst in industry (Raney® nickel with a nickel composition of 61%). Moreover, the SG-structured Ni with high efficiency possesses high selectivity for hydrogenation between cyclohexene and toluene. In contrast to noble metal catalysts, such as palladium and platinum, at low reaction temperatures (for instance, 50 bar and 80 °C), the SG-structured Ni could selectively hydrogenate the unsaturated double bond of cyclohexene without hydrogenating the aromatic ring of toluene (see Table 1 for details). Palladium and platinum are well-known high-efficiency catalysts, and the hydrogenation of toluene and organics with unsaturated double-bonds will simultaneously occur in low-temperature reaction conditions44,45. As demonstrated above, the SG-structured Ni nanoporous sphere with high activity and excellent selectivity indeed meets the criteria of high efficiency catalysis. Most importantly, for a cost-effective process, it is essential to possess catalytic recyclability; owing to the robust structure of the SG continuous network, the structure would be maintained after the hydrogenation reaction, which could be reused without a huge decay in efficiency after many cycles. Additionally, due to their microscale dimensions, the SG-structured Ni nanoporous spheres can be simply suspended in the solution for hydrogenation reaction and then simply recycled by using a magnet to repeatedly collect the spheres by applying a magnetic field and then dispersing the spheres in the suspension by stirring (see Video S1 for demonstration). Note that the SG-structured Ni nanoporous sphere is safe in the atmosphere, while Raney® nickel, a fine grain of nickel-aluminum alloy that has a low density due to its incorporation of hydrogen, is flammable. Nickel-aluminum alloy is a porous structure with high efficiency after the activation process during fabrication that simultaneously fills hydrogen into its pores, which results in low density and flammability. Therefore, Raney® nickel should be handled in an inert atmosphere to prevent the ignition problem that often causes severe problems in safety.
Conclusions
In conclusion, MNSs with SG structures can be successfully fabricated by using a DG-structured PS template for electroless plating through nucleation and growth mechanisms using a low nucleus density strategy for reduction. Furthermore, by controlling the deposition time for the reduction of Ni, the sphere sizes of the MNSs can be fine-tuned. Consequently, free-standing SG-structured Ni spheres with high specific surface areas, uniform pore sizes, and microscale particle sizes can be obtained. As exemplified in this study, the fabricated Ni nanoporous sphere can serve as a high-activity catalyst for the hydrogenation process with good recyclability. As a result, the fabricated SG-structured Ni nanoporous spheres are appealing in a wide variety of applications because of their network shapes, robust properties, single networks, uniform nanoscale pore sizes, and microscale particle sizes, which give them excellent recyclability via magnetic fields.
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Acknowledgements
The authors would like to thank the National Science Council of the Republic of China, Taiwan, for financially supporting this research under Contract No. Grant NSC 106-2119-M-007-010-, and the National Synchrotron Radiation Research Center (NSRRC) for its assistance in the synchrotron SAXS experiments. This work was supported in part by the Ministry of Education, Taiwan, R.O.C., under the Higher Education Sprout Project.
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Single Gyroid-Structured Metallic Nanoporous Sphere from Double Gyroid-Forming Block Copolymer via Templated Electroless Plating
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Yang, KC., Yao, CT., Huang, LY. et al. Single gyroid-structured metallic nanoporous spheres fabricated from double gyroid-forming block copolymers via templated electroless plating. NPG Asia Mater 11, 9 (2019). https://doi.org/10.1038/s41427-019-0108-z
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DOI: https://doi.org/10.1038/s41427-019-0108-z
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