Abstract
Molybdenum(IV) complexes supported on partially p-mercaptomethyl substituted cross-linked polystyrene were prepared. A binary system of the above molybdenum complexes and ferredoxin model compound, [Fe4S4(SPh)4]2−, has excellent catalytic activity for the reduction of acetylene, compared to the corresponding unsupported molybdenum complexes. The reduction and reductive cleavage of dinitrogen were also investigated as a nitrogenase model reaction.
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S. P. Cramer, K. O. Hodgson, W. O. Gillum, and L. E. Mortenson, J. Am. Chem. Soc., 100, 3398 (1978).
S. P. Cramer, W. O. Gillum, K. O. Hodgson, L. E. Mortenson, E. O. Stiefel, J. R. Chisnell, W. J. Brill, and V. K. Shah, J. Am. Chem. Soc., 100, 3814 (1978).
V. K. Shah, J. R. Chisnell, and W. J. Brill, Biochem. Biophys. Res. Commun., 81, 232 (1978).
G. N. Schrauzer and P. A. Doemeny, J. Am. Chem. Soc., 93, 1608 (1971).
P. R. Robinson, E. L. Moorehead, B. J. Weathers, E. A. Ufkes, T. M. Vickrey, and G. N. Schrauzer, J. Am. Chem. Soc., 99, 3657 (1977).
G. N. Schrauzer, G. W. Kiefer, K. Tano, and P. A. Doemeny, J. Am. Chem. Soc., 96, 641 (1974).
B. J. Weathers, J. H. Grate, N. A. Strampach, and G. N. Schrauzer, J. Am. Chem. Soc., 101, 925 (1979).
N. Oguni, S. Shimazu, and A. Nakamura, Polym. J., 12, 891 (1980).
D. C. Bradley and M. H. Chisholm, J. Chem. Soc., Sect. A, 2741 (1971).
M. H. Chisholm, W. W. Reichert, and P. Thornton, J. Am. Chem. Soc., 100, 2744 (1978).
R. Pribil and M. Malat, Collect. Czech. Chem. Commun., 15, 120 (1950).
“The clinical chemical analysis II” (Analytical Library vol. 3), The Japan Society for Chemical Analysis, Ed., Tokyo Kagaku Dojin, 1968, p 27 and p 463.
J. Hyde, L. Magin, and J. Zubieta, Chem. Commun., 204 (1980).
J. L. Corbin, N. Pariyadath, and E. I. Stiefel, J. Am. Chem. Soc., 98, 7862 (1977).
M. H. Chisholm, F. A. Cotton, B. A. Frenz, W. W. Reichert, L. W. Shive, and B. R. Stults, J. Am. Chem. Soc., 98, 4469 (1976).
M. H. Chisholm, F. A. Cotton, C. A. Murillo, and W. W. Reichert, Inorg. Chem., 16, 1801 (1977).
S. Otsuka and M. Kamata, “Molybdenum Chemistry of Biological Significance,” W. E. Newton and S. Otsuka, Ed., “Proceedings of the International Symposium,” Lake Biwa, Kyoto, April 1979, Plenum Press, New York, N.Y., 1980, p 229.
D. A. Ledwith and F. A. Schultz, J. Am. Chem. Soc., 97, 6591 (1975).
N. T. Denisov, A. E. Shilov, N. I. Shuvalova, and T. P. Panova, React. Kinet. Catal. Lett., 2, 237 (1975).
R. H. Grubbs, C. Gibbons, L. C. Kroll, W. D. Bonds Jr., and C. H. Brubaker Jr., J. Am. Chem. Soc., 95, 2373 (1973).
J. Reed, P. Eisenberger, B-K. Teo, and B. M. Kincaid, J. Am. Chem. Soc., 100, 2375 (1978).
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Oguni, N., Shimazu, S., Iwamoto, Y. et al. Electron Transfer Reduction of Acetylene by Catalysis of Partially p-Mercaptomethyl Substituted Polystyrene–Molybdenum(IV) Complexes in Protic Solvent. Polym J 13, 845–852 (1981). https://doi.org/10.1295/polymj.13.845
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DOI: https://doi.org/10.1295/polymj.13.845