Optical temperature sensing based on making fluorescence intensity ratio measurements of two thermally linked transitions in rare-earth-doped materials is now a well-established concept. However, to date, the sensitivity of the approach has been a limitation. Researchers from Harbin Institute of Technology in China now report that the sensitivity of the approach can be dramatically improved by employing ferroelectric Pr3+-doped (K0.5Na0.5)NbO3 (also known as KNN:Pr3+) as a sensing medium. The team achieve an ultrahigh sensitivity of 7,997/T2, the highest value achieved so far and more than twice that of earlier work, by measuring the intensity ratio of the 1D2–3H4 (603 nm) and 3P0–3H4 (489 nm) transitions under excitation with 325 nm ultraviolet light. Photoluminescence measurements made between 293 and 456 K confirm the validity of the approach.
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Graydon, O. Temperature sensitivity boost. Nature Photon 10, 207 (2016). https://doi.org/10.1038/nphoton.2016.60
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DOI: https://doi.org/10.1038/nphoton.2016.60