Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Article
  • Published:

Model calculations of the relative effects of CFCs and their replacements on stratospheric ozone

Abstract

Because chlorine has been linked to the destruction of stratospheric ozone, the use of many fully halogenated compounds, such as the chloro-fluorocarbons CFC-11 and -12, is restricted by international agreement. Hydrohalocarbons are under intensive development as replacements for CFCs. Because they contain hydrogen, these gases are susceptible to tropospheric destruction which significantly shortens their atmospheric lifetimes. Model calculations show that chlorine-containing hydrohalocarbons have less effect on ozone, by an order of magnitude, than their regulated counter-parts.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Makide, Y. & Rowland, F. S. Proc. natn. Acad. Sci. U.S.A. 78, 5933–5937 (1981).

    Article  ADS  CAS  Google Scholar 

  2. Fisher, D. A., Hales, C. H., Wang, W.-C., Ko, M. K. W. & Sze, N. D. Nature 344, 513–516 (1990).

    Article  ADS  CAS  Google Scholar 

  3. Wofsy, S. C. & McElroy, M. B. Can. J. Chem. 52, 1582–1591 (1974).

    Article  CAS  Google Scholar 

  4. Donahue, T. M., Cicerone, R. J., Liu, S. C. & Chameides, W. L. Geophys. Res. Lett. 3, 105–108 (1976).

    Article  ADS  CAS  Google Scholar 

  5. Robins, D. E. & Stolarski, R. S. Geophys. Res. Lett. 3, 603–606 (1976).

    Article  ADS  Google Scholar 

  6. Wuebbles, D. J. Rep. UCID-18924 (Lawrence Livermore National Laboratory, Livermore, 1981).

  7. Wuebbles, D. J. J. geophys. Res. 88, 1433–1443 (1983).

    Article  ADS  CAS  Google Scholar 

  8. Hammitt, J. K. et al., Nature 330, 711–716 (1987).

    Article  ADS  CAS  Google Scholar 

  9. Rognerud, B., Isaksen, I. S. A. & Strodal, F. in Ozone in the Atmosphere (eds Bojkov, R. D. & Fabian, P.) 609–612 (Deepak Publishing, Hampton, Virginia, 1989).

    Google Scholar 

  10. Ko, M. K. W., Sze, N. D., Livshits, M., McElroy, M. B. & Pyle, J. A. J. atmos. Sci. 41, 2381–2408 (1984).

    Article  ADS  CAS  Google Scholar 

  11. Ko, M. K. W., Tung, K. K., Weisenstein, D. K. & Sze, N. D. J. geophys. Res. 90, 2313–2329 (1985).

    Article  ADS  CAS  Google Scholar 

  12. Kinnison, D., Johnston, H. & Wuebbles, D. J. J. geophys. Res. 93, 14165–14175 (1988).

    Article  ADS  CAS  Google Scholar 

  13. Miller, C., Filkin, D. L., Owens, A. J., Steed, J. M. & Jesson, J. P. J. geophys. Res. 86, 12039–12065 (1981).

    Article  ADS  CAS  Google Scholar 

  14. Miller, C., Steed, J. M., Filkin, D. L. & Jesson, J. P. Atmos Environ. 15, 729–942 (1981).

    Article  ADS  CAS  Google Scholar 

  15. Stordal, F., Isaksen, I. S. A. & Horntveth, K. J. geophys. Res. 90, 5757–5776 (1985).

    Article  ADS  CAS  Google Scholar 

  16. Sze, N. D. & Ko, M. K. W. Atmos. Envir. 15, 1301–1367 (1981).

    Article  CAS  Google Scholar 

  17. Wuebbles, D. J. & Kinnison, D. E. in Ozone in the Atmosphere (eds Bojkov, R. D. & Fabian, P.) 605–608 (Deepak Publishing, Hampton, Virginia, 1989).

    Google Scholar 

  18. Sze, N. D. Science 195, 673–675 (1977).

    Article  ADS  CAS  Google Scholar 

  19. Chameides, W. L., Liu, S. C. & Cicerone, R. C. J. geophys. Res. 82, 1795–1798 (1977).

    Article  ADS  CAS  Google Scholar 

  20. Hampson, R. F., Kurylo, M. J. & Sander, S. P. in World Meteorological Organization. Scientific Assessment of Stratospheric Ozone: 1989, Global Ozone Research and Monitoring Project—Rep. No. 20, Vol. II, 47, Appendix: AFEAS Report (Geneva, 1989).

    Google Scholar 

  21. Molina, M. J. in World Meteorological Organization, Scientific Assessment of Stratospheric Ozone: 1989, Global Ozone Research and Monitoring Project—Rep. No. 20, Vol. II, 111, Appendix: AFEAS Report (Geneva, 1989).

    Google Scholar 

  22. DeMore, W. B. et al. JPL Publication 87–41 (Jet Propulsion Laboratory, Pasadena, 1987).

    Google Scholar 

  23. Davidson, J. A., Schiff, H. I., Brown, T. J. & Howard, C. J. J. chem. Phys. 69, 4277–4279 (1978).

    Article  ADS  CAS  Google Scholar 

  24. Hubrich, C. & Stuhl, F. J. Photochem. 12, 93–107 (1980).

    Article  CAS  Google Scholar 

  25. Prinn, R. et al. Science 238, 945–950 (1987).

    Article  ADS  CAS  Google Scholar 

  26. Watson, R. T., Prather, M. J. & Kurylo, M. J. Present state of knowledge of the upper atmosphere 1988: An assessment report (to congress), NASA Reference Publication 1208 (Washington, 1988).

  27. Solomons, S. Rev. Geophys. 26, 141–148 (1988).

    ADS  Google Scholar 

  28. Sze, N. D. et al. J. geophys. Res. 94, 11521–112528 (1989).

    Article  ADS  CAS  Google Scholar 

  29. Tuck, A. F. J. geophys. Res. 94, 11687–11737 (1989).

    Article  ADS  CAS  Google Scholar 

  30. Fisher, D. A. et al. in World Meteorological Organization, Scientific Assessment of Stratospheric Ozone: 1989, Global Ozone Research and Monitoring Project—Rep. No. 20, Vol. 11, 297, Appendix: AFEAS Report (Geneva, 1989).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fisher, D., Hales, C., Filkin, D. et al. Model calculations of the relative effects of CFCs and their replacements on stratospheric ozone. Nature 344, 508–512 (1990). https://doi.org/10.1038/344508a0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1038/344508a0

This article is cited by

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing