Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • Article
  • Published:

Stability of Binuclear Complexes

Abstract

Empirical arguments lead to a relationship between the stability constant for the formation of a binuclear complex MXM(2mx)+, and that for the corresponding mononuclear complex MX(mx)+. As KMX increases along a series of metal ions Mm+, with a given ligand Xx, it is predicted that KMXM will pass through a maximum value, in agreement with available data.

This is a preview of subscription content, access via your institution

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Similar content being viewed by others

References

  1. Manning, P. V., Jarnagin, R. C., and Silver, M., J. Phys. Chem., 68, 265 (1964).

    Article  CAS  Google Scholar 

  2. Movius, W. G., and Linck, R. G., J. Amer. Chem. Soc., 91, 5394 (1969).

    Article  CAS  Google Scholar 

  3. Sillén, L. G., and Martell, A. E., Stability Constants, second ed. (London, 1964); Lamb, A. B., and Mysels, K. J., J. Amer. Chem. Soc., 67, 468 (1945).

    Google Scholar 

  4. Basolo, F., and Pearson, R. G., Mechanisms of Inorganic Reactions, 216, second ed. (New York, 1967).

    Google Scholar 

  5. Biedermann, G., and Ohtaki, H., quoted by Arnek, R., Acta Chem. Scand., 22, 1102 (1968); Schellenburg, M., and Schwarzenbach, G., Proc. 71CCC, 157 (Stockholm, 1962).

    Article  Google Scholar 

  6. Mattock, G., J. Amer. Chem. Soc., 76, 4835 (1954).

    Article  CAS  Google Scholar 

  7. Kakihana, H., and Sillén, L. G., Acta Chem. Scand., 10, 985 (1956).

    Article  CAS  Google Scholar 

  8. Carell, B., and Olin, Å, Acta Chem. Scand., 15, 1875 (1961).

    Article  CAS  Google Scholar 

  9. Bertin, F., Thomas, G., and Merlin, J-C., CR Acad. Sci., 260, 1670 (1965).

    CAS  Google Scholar 

  10. Bertin, F., Thomas, G., and Merlin, J-C., Bull. Soc. Chim. France, 2393 (1967).

  11. Ohtaki, H., Inorg. Chem., 6, 808 (1967); Ohtaki, H., and Kato, H., ibid., 6, 1935 (1967).

    Article  CAS  Google Scholar 

  12. Mesmer, R. E., and Baes, C. F., Inorg. Chem., 6, 1951 (1967).

    Article  CAS  Google Scholar 

  13. Schwarzenbach, G., Pure Appl. Chem., 5, 377 (1962).

    Article  CAS  Google Scholar 

  14. Hietanen, S., and Sillén, L. G., Acta Chem. Scand., 18, 1015 (1964).

    Article  CAS  Google Scholar 

  15. Thompson, G., thesis, Univ. California (1964).

  16. Olin, Å, Acta Chem. Scand., 14, 126 (1960).

    Article  CAS  Google Scholar 

  17. Pajdowski, L., and Olin, Å, Acta Chem. Scand., 16, 983 (1962); Olin, Å, ibid., 14, 814 (1960).

    Article  CAS  Google Scholar 

  18. Pan, K., and Hseu, T. M., Bull. Chem. Soc. Jap., 28, 162 (1955).

    Article  CAS  Google Scholar 

  19. Hietanen, S., and Sillén, L. G., Acta Chem. Scand., 13, 533 (1959).

    Article  Google Scholar 

  20. Dunsmore, H. S., Hietanen, S., and Sillén, L. G., Acta Chem. Scand., 17, 2644 (1963).

    Article  Google Scholar 

  21. Kabel, R. L., and Johanson, L. N., J. Chem. Eng. Data, 6, 496 (1961).

    Article  CAS  Google Scholar 

  22. Kabel, R. L., Diss. Abs., 22, 1539 (1961).

    Google Scholar 

  23. Skinner, H. A., J. Chem. Soc., 4396 (1962).

  24. Pilcher, G., Skinner, H. A., Pell, A. S., and Pope, A. E., Trans. Faraday Soc., 59, 316 (1963).

    Article  CAS  Google Scholar 

  25. Landolt-Börnstein, Zahlenwerte und Funktionen, sixth ed., 2 (1961).

    MATH  Google Scholar 

  26. Intern. Crit. Tables, 5, 81 (1929); Eucken, A., and Franck, E. U., Z. Elektrochem., 52, 195 (1948).

    Google Scholar 

  27. Butler, J. A. V., Trans. Faraday Soc., 33, 229 (1936).

    Article  Google Scholar 

  28. Deno, N. C., and Turner, J. O., J. Org. Chem., 31, 1969 (1966).

    Article  CAS  Google Scholar 

  29. Cannon, R. D., and Earley, J. E., J. Amer. Chem. Soc., 88, 1872 (1966).

    Article  CAS  Google Scholar 

  30. Martell, A. E., Proc. Symp. Coord. Chem., Tihany (Hungary), 173 (1964).

  31. Beck, M. T., Coord. Chem. Rev., 3, 91 (1968).

    Article  CAS  Google Scholar 

  32. Bogucki, R. F., and Martell, A. E., J. Amer. Chem. Soc., 80, 4170 (1958).

    Article  CAS  Google Scholar 

  33. Carey, G. H., and Martell, A. E., J. Amer. Chem. Soc., 90, 32 (1968).

    Article  CAS  Google Scholar 

  34. Jordan, R. B., Sargeson, A. M., and Taube, H., Inorg. Chem., 5, 1091 (1966).

    Article  CAS  Google Scholar 

  35. Deutsch, E., and Taube, H., Inorg. Chem., 7, 1532 (1968).

    Article  CAS  Google Scholar 

  36. Paul, M. A., and Long, F. A., Chem. Rev., 57, 1 (1957).

    Article  CAS  Google Scholar 

  37. Young, T. F., and Blatz, L. A., Chem. Rev., 44, 93 (1949).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

CANNON, R. Stability of Binuclear Complexes. Nature 228, 644–647 (1970). https://doi.org/10.1038/228644a0

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1038/228644a0

Comments

By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing