Abstract
THE oxidation of sulphur compounds in fuel to form sulphur dioxide, and the further oxidation of a small proportion of this to sulphur trioxide, give rise to problems of atmospheric pollution and of corrosion. The severe corrosion frequently experienced in those zones of boilers where the combustion products have become relatively cool is related to the sulphur trioxide of the flue gases, and the formation of sulphur trioxide in boilers has therefore been subjected to extensive investigations. The mechanisms generally held to be responsible for the production of the greater part of the sulphur trioxide detected in boiler flue gases are: (1) oxidation of sulphur dioxide by oxygen atoms in the flame; and (2) catalytic oxidation of sulphur dioxide at surfaces in the post-flame region.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Laxton, J. W., and Jackson, P. J., J. Inst. Fuel, 37, 12 (1964).
Lewis, B., and von Elbe, G., Combustion, Flames and Explosions of Gases, second ed., 88 (Academic Press, New York and London, 1961).
Boreshov, G. K., and Illarionov, V. V., Zhur. Fiz. Khim., 14, 1428 (1940).
Cullis, C. F., Henson, R. M., and Trimm, D. L. (personal communication).
Kaufman, F., Proc. Roy. Soc., A, 247, 123 (1958).
Levy, A., and Merryman, E. L., paper 64–32, Autumn meeting, Western States Section of the Combustion Institute, Salt Lake City, 1964.
Webster, P., and Walsh, A. D., Tenth Symp. (Intern.) on Combustion, 463 (The Combustion Institute, Pittsburgh, 1965).
Kaufman, F., Progress in Reaction Kinetics, edit. by Porter, G., 1, 26 (Pergamon Press, 1961).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
SHAW, J., GREEN, P. Oxidation of Sulphur Dioxide in Air at 950° C: Co-operative Influence of Carbon Monoxide and Nitric Oxide. Nature 211, 1171–1172 (1966). https://doi.org/10.1038/2111171a0
Issue Date:
DOI: https://doi.org/10.1038/2111171a0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.