Abstract
THE oxide AgO is a diamagnetic, monoclinic, stoichiometric Ag(I)–Ag(III) oxide1,2. Its behaviour in acid solutions is well known: it dissolves as bivalent silver with 1.98 effective magnetons perion3,4. The nature and parameters of the magnetic complex do not depend critically on the stabilizing acid5, namely, nitric, sulphuric, perchloric, hydrofluoric or orthophosphoric. It has cylindrical magnetic symmetry, as most of the bivalent silver complex compounds6. The dissolution of AgO in alkaline solutions, however, is a well-known process in regard to the solubility, although the nature of the product is only speculative. Studies of the variation of the solubility with pH have led to the formulation of the dissolution products:
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
McMillan, J. A., J. Inorg. Nuclear Chem., 13, 28 (1960).
Scatturin, V., Bellon, P., and Salkind, A. J., Ricerca Sci., 30, 1034 (1960).
Noyes, A. A., Pitzer, K. S., and Dunn, C. L., J. Amer. Chem. Soc., 57, 1229 (1935).
McMillan, J. A., and Smaller, B., J. Chem. Phys., 35, 1698 (1961).
McMillan, J. A., and Milá de la Roca, G., J. Inorg. Nuclear Chem. (to be published).
Milá de la Roca, G., and McMillan, J. A., Bull. Amer. Phys. Soc., 7, 183 (1962) (to be published elsewhere).
Dirkse, T. P., and Wiers, B. J., J. Electrochem. Soc., 106, 284 (1959).
McMillan, J. A., Chem. Revs., 62, 65 (1962).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
MCMILLAN, J. Dissolution of AgO in Acid and Alkaline Media. Nature 195, 594–595 (1962). https://doi.org/10.1038/195594a0
Issue Date:
DOI: https://doi.org/10.1038/195594a0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.