Abstract
THE formation and decomposition of a higher hydrogen peroxide H2O4 has been described in recent Russian literature. Much of this work dealt with the existence of condensed HO2 radicals or molecular H2O4 at low temperatures ; for example, Kobozev et al., Reznitskii et al., and Gorbanev1 investigated the reaction between atomic hydrogen and liquid ozone at −196°C. Calorimetric and electron spin resonance measurements are quoted as evidence for the existence of hydrogen superoxide H2O4 which decomposes spontaneously at −115°C. into hydrogen peroxide and oxygen.
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Kobozev, N. I., Nekrasov, L. I., and Yeremin, Ye. N., Zhur. Fiz. Khim., 30 (11), 2580 (1956). Kobozev, N. I., Skorokhodov, I. I., Nekrasov, L. I., and Makarova, E. I., Zhur. Fiz. Khim., 31 (8), 1843 (1957). C.T.S. Translation No. 564. Reznitskii, L. A., Khomykov, K. G., Nekrasov, L. I., and Skorokhodov, I. I., Zhur. Fiz. Khim., 32 (1), 87 (1958). Gorbanev, A. I., Zhur. Fiz. Khim., 31 (2), 515 (1957).
Astakhov, K. V., and Getzov, A. G., Doklady Akad. Nauk S.S.S.R., 81, 43 (1951).
Kruglyakova, K. E., and Emanuel, N. M., Doklady Akad. Nauk S.S.S.R., 83, 593 (1952).
Stadnik, P. M., Doklady Akad. Nauk S.S.S.R., 87, 445 (1952).
Purmal, A. P., Zhur. Fiz. Khim., 29 (5), 846 (1955).
Mckinley, J. D., Tech. Report No. 9, Jan. 1954. James Forrestal Res. Centre, Princeton, J. Chem. Phys., 22, 1258 (1954).
Mironov, K. E., and Danilova, M. S., Zhur. Neorg. Khim., 3 (12), 2807 (1958).
Metschl, J., J. Phys. Chem., 28, 417 (1924).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
MARSHALL, J., RUTLEDGE, P. A Higher Hydrogen Peroxide, H2O4?. Nature 184, 2013–2014 (1959). https://doi.org/10.1038/1842013a0
Issue Date:
DOI: https://doi.org/10.1038/1842013a0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.
